Abstract
The kinetics of supramolecular crystallization of concentrated suspensions is three-dimensional and follows the Avrami-Erofeev equation: A=1-exp[-(kt)m], where m=4. The rate constant k is proportional to the probability of the appearance of a crystallization center in unit volume in unit time and the linear crystal growth rate, which is determined experimentally.
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Serdobintseva, V.V., Danilyuk, A.F., Vosel, S.V. et al. Kinetics of supramolecular crystallization of concentrated suspensions of monodisperse spherical silica particles. React Kinet Catal Lett 68, 387–391 (1999). https://doi.org/10.1007/BF02475528
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DOI: https://doi.org/10.1007/BF02475528