Abstract
Carbonylation of chlorobenzene to 4-chlorobenzophenone and/or benzoyl chloride may be catalyzed by PdCl2 in the presence of Lewis acids MCl3 (M=Al, Ga). Such a C−Cl bond carbonylation with a phosphine-free catalyst was previosly unknown.
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Noskov, Y.G., Petrov, E.S. Palladium-catalyzed carbonylation of chlorobenzene in the presence of lewis acids. React Kinet Catal Lett 64, 359–363 (1998). https://doi.org/10.1007/BF02475357
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DOI: https://doi.org/10.1007/BF02475357