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Selective hydrogenation of nitrobenzene top-Aminophenol by the polymer-supported palladium-based mono- and bimetallic catalyst

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Abstract

In acidic reaction medium, polymer-supported monometallic palladium catalyst, PVP-PdCl2 [(PVP=poly(N-vinyl-pyrrolidone)], is used to catalyze the hydrogenation of nitrobenzene top-aminophenol and aniline. The addition of a second transition metal compound or a very small amount of 2-mercaptopyrimidine gives rise to an increase in the selectivity forp-aminophenol.

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Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, 116023, Dalian, P.R. China

    Yan Gao, Fudong Wang, Shijian Liao & Daorong Yu

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  1. Yan Gao
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  2. Fudong Wang
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  3. Shijian Liao
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  4. Daorong Yu
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Gao, Y., Wang, F., Liao, S. et al. Selective hydrogenation of nitrobenzene top-Aminophenol by the polymer-supported palladium-based mono- and bimetallic catalyst. React Kinet Catal Lett 64, 351–357 (1998). https://doi.org/10.1007/BF02475356

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  • DOI: https://doi.org/10.1007/BF02475356

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