Abstract
The glass-forming ability and crystallization behaviour of lithium borate compositions, in the diborate to metaborate range, were studied. In particular, the nature and sequence of formation of crystalline phases and the tendency towards devitrification were investigated as functions of temperature, thermal history and batch composition. It was found that the sequence of crystalline phase formation was sensitive to all of the three latter factors, and it was observed that under certain conditions metastable defect structures of the metaborate can appear.
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H. L. Tuller, D. P. Button andD. R. Uhlmann,J. Non-Cryst. Solids 40 (1980) 93.
M. D. Ingram,Phys. Chem. Glasses 28 (1987) 215.
K. Otto,ibid. 7 (1966) 29.
Y. Ito, K. Miyauchi andT. Oi,J. Non-Cryst. Solids 57 (1983) 389.
D. P. Button, P. K. Moon, H. L. Tuller andD. R. Uhlmann,Glastech Ber. 56K (1983) 856.
M. Tatsumisago, K. Yoneda, N. Machida andT. Minami,J. Non-Cryst. Solids 95/96 (1987) 857.
J. Shelby,J. Amer. Ceram. Soc. 66 (1982) 225.
E. I. Kamitsos, M. A. Karakassides andG. D. Chryssikos,Phys. Chem. Glasses 28 (1987) 203.
Idem., J. Phys. Chem. 90 (1986) 4528.
B. S. R. Sastry andF. A. Hummel,J. Amer. Ceram. Soc. 41 (1957) 7.
H. Franz,ibid. 49 (1966) 473.
W. H. Zachariasen,Acta Crystallogr. 17 (1964) 749.
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Goktas, A.A., Neilson, G.F. & Weinberg, M.C. Crystallization of lithium borate glasses. J Mater Sci 27, 24–28 (1992). https://doi.org/10.1007/BF02403639
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DOI: https://doi.org/10.1007/BF02403639