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Crystallization of lithium borate glasses

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Abstract

The glass-forming ability and crystallization behaviour of lithium borate compositions, in the diborate to metaborate range, were studied. In particular, the nature and sequence of formation of crystalline phases and the tendency towards devitrification were investigated as functions of temperature, thermal history and batch composition. It was found that the sequence of crystalline phase formation was sensitive to all of the three latter factors, and it was observed that under certain conditions metastable defect structures of the metaborate can appear.

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References

  1. H. L. Tuller, D. P. Button andD. R. Uhlmann,J. Non-Cryst. Solids 40 (1980) 93.

    Article  CAS  Google Scholar 

  2. M. D. Ingram,Phys. Chem. Glasses 28 (1987) 215.

    CAS  Google Scholar 

  3. K. Otto,ibid. 7 (1966) 29.

    CAS  Google Scholar 

  4. Y. Ito, K. Miyauchi andT. Oi,J. Non-Cryst. Solids 57 (1983) 389.

    Article  CAS  Google Scholar 

  5. D. P. Button, P. K. Moon, H. L. Tuller andD. R. Uhlmann,Glastech Ber. 56K (1983) 856.

    Google Scholar 

  6. M. Tatsumisago, K. Yoneda, N. Machida andT. Minami,J. Non-Cryst. Solids 95/96 (1987) 857.

    Article  Google Scholar 

  7. J. Shelby,J. Amer. Ceram. Soc. 66 (1982) 225.

    Google Scholar 

  8. E. I. Kamitsos, M. A. Karakassides andG. D. Chryssikos,Phys. Chem. Glasses 28 (1987) 203.

    CAS  Google Scholar 

  9. Idem., J. Phys. Chem. 90 (1986) 4528.

    Article  CAS  Google Scholar 

  10. B. S. R. Sastry andF. A. Hummel,J. Amer. Ceram. Soc. 41 (1957) 7.

    Google Scholar 

  11. H. Franz,ibid. 49 (1966) 473.

    CAS  Google Scholar 

  12. W. H. Zachariasen,Acta Crystallogr. 17 (1964) 749.

    Article  CAS  Google Scholar 

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Goktas, A.A., Neilson, G.F. & Weinberg, M.C. Crystallization of lithium borate glasses. J Mater Sci 27, 24–28 (1992). https://doi.org/10.1007/BF02403639

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  • DOI: https://doi.org/10.1007/BF02403639

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