Skip to main content
SpringerLink
Log in

A comparison of phase equilibria in some II-IV-VI compounds based on PbTe

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The solubilities of the group II elements Cd, Zn, Hg, Ca and Mg in PbTe are compared over the temperature range 250 to 800° C. Cd, Zn and Mg have retrograde solubilities whilst Hg and Ca are virtually insoluble in “as-grown” material. A consequence of these solubilities is a change in the properties of the alloys compared with PbTe. Thus the phase widths of the Cd/PbTe, Mg/PbTe and Zn/PbTe systems differ from that of PbTe. With the exception of the Zn/PbTe system, (where there is reasonable evidence to support the solubility of Zn in PbTe) there is a significant change in all measured electrical properties compared with PbTe.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. A. Kröger, “The Chemistry of Imperfect Crystals” (North Holland, Amsterdam, 1964).

    Google Scholar 

  2. W. Albers andC. Hass,Philips Rev. 30 (1969) 82.

    CAS  Google Scholar 

  3. N. J. Parada andG. W. Pratt,Phys. Rev. Letters 22 (1969) 180.

    Article  CAS  Google Scholar 

  4. M. P. Gomez, D. A. Stevenson andR. A. Huggins,J. Phys. Chem. Solids 32 (1971) 335.

    Article  CAS  Google Scholar 

  5. T. D. George andJ. B. Wagner,J. Appl. Phys. 42 (1971) 220.

    Article  CAS  Google Scholar 

  6. M. S. Seltzer andJ. B. Wagner,J. Chem. Phys. 36 (1962) 130;J. Phys. Chem. Solids 24 (1963) 1528.

    Article  CAS  Google Scholar 

  7. G. Simkovich andJ. B. Wagner,ibid 38 (1963) 1368.

    Article  CAS  Google Scholar 

  8. K. R. Zanio andJ. B. Wagner,J. Appl. Phys. 39 (1968) 5686.

    Article  CAS  Google Scholar 

  9. R. F. Brebrick andR. S. Allgaier,J. Chem. Phys. 32 (1960) 1826.

    Article  CAS  Google Scholar 

  10. R. F. Brebrick andE. Gubner,ibid 36 (1962) 1283.

    Article  CAS  Google Scholar 

  11. E. Miller, K. Komarek andI. Cadoff,J. Appl. Phys. 32 (1961) 2487.

    Google Scholar 

  12. T. L. Kovalchik andIu. P. Maslakovets,Sov. Phys. Tech. Phys. 1 (1956) 2337.

    Google Scholar 

  13. B. J. Sealy andA. J. Crocker,J. Mater. Sci. 8 (1973) 1737.

    Article  CAS  Google Scholar 

  14. R. F. Brebrick andE. Gubner,J. Chem. Phys. 36 (1962) 170.

    Article  CAS  Google Scholar 

  15. N. Ohashi andK. Igaki,Trans. J.I.M. 5 (1964) 94.

    CAS  Google Scholar 

  16. A. Calawa, T. C. Harmon, M. Finn andP. Youtz,Trans. Met. Soc. AIME 242 (1968) 374.

    CAS  Google Scholar 

  17. J. Bloem andF. A. Kröger,Z. Phys. Chem. 7 (1956) 1.

    Article  CAS  Google Scholar 

  18. A. J. Crocker,J. Mater. Sci. 3 (1968) 534.

    Article  CAS  Google Scholar 

  19. A. J. Rosenberg, R. Grierson, J. C. Wooley andP. Nikolic,Trans. Met. Soc. AIME 230 (1964) 342.

    CAS  Google Scholar 

  20. A. J. Crocker andB. J. Sealy,J. Phys. Chem. Solids 33 (1972) 2183.

    CAS  Google Scholar 

  21. B. J. Sealy andA. J. Crocker,J. Mater Sci 8 (1973) 1247.

    Article  CAS  Google Scholar 

  22. V. G. Vanyarkho,et al,Vestnik Moskov. Univer. 6 (1968) 108.

    Google Scholar 

  23. L. M. Rogers andA. J. Crocker,J. Phys. D. 4 (1971) 1016.

    Article  CAS  Google Scholar 

  24. J. J. Van Der Pauw,Philips Res. Rep. 13 (1938) 1.

    Google Scholar 

  25. H. E. Bates, F. Wald andM. Weinstein,Advanced Energy Conversion 7 (1968) 275.

    Article  CAS  Google Scholar 

  26. R. E. Honig andD. A. Kramer,RCA Rev. 30 (1969) 285.

    CAS  Google Scholar 

  27. L. M. Rogers, Ph.D. Thesis (1970) CNAA.

  28. E. Miller, K. Komarek andI. Cadoff,Trans. Met. Soc. AIME 215 (1959) 882.

    CAS  Google Scholar 

Download references

Author information

Author notes

  1. B. J. Sealy

    Present address: Department of Physics, University of Surrey, Guildford, UK

  2. A. J. Crocker

    Present address: Division of Physics, Thames Polytechnic, Wellington Street, London SE18, UK

Authors and Affiliations

  1. Zenith Radio Research Coporation (UK) Ltd, Stanmore, Middlesex

    B. J. Sealy & A. J. Crocker

Authors
  1. B. J. Sealy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. J. Crocker
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sealy, B.J., Crocker, A.J. A comparison of phase equilibria in some II-IV-VI compounds based on PbTe. J Mater Sci 8, 1731–1736 (1973). https://doi.org/10.1007/BF02403524

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02403524

Keywords

Search

Navigation