Abstract
The hyperfine interactions of111Cd in gallium oxide doped with111In have been studied as a function of temperature (300–1323 K) by means of the time differential perturbed angular correlation technique. The observed hyperfine interactions are assigned to the the β — form of gallium oxide. X-ray diffraction analysis support this conclusion. It is found that indium replace gallium at only one site of both possible sites in the monoclinic β — structure. This site is probably the sixfold corrdinated one. On the other hand, a time dependent interaction is detected at temperatures below 800 K.
Similar content being viewed by others
References
A.G. Bibiloni, C.P. Massolo, J. Desimoni, L.A. Mendoza Zélis, F.H. Sánchez, A.F. Pasquevich and A.R. López Garcia. Phys. Rev. B32(1985)2393.
S. Geller, J. Chem. Phys. 33,676(1960).
Hyung-Gon Kim and Wha-Tek Kim, J. Appl. Phys. 62(1987)2000.
H.H. Tippins, Phys. Rev. 137A(1965)865.
R. Büscher and G. Lehmann, Z. Naturforsch 12a(1987)67.
J.M. Trooster and A. Dymanus, Phys. stat. sol. 24(1967)187
CRC Handbook of Chemistry and Physics, ed. R.C. Weast and M.J. Astle (CRC Press, Florida, 1981), p. B102.
N.N. Greenwood and H. Earnshaw, in Chemistry of the elements (Pergamon Press, New York, 1969), p. 278.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pasquevich, A.F. Preferential site occupation of indium in β-Ga2O3 . Hyperfine Interact 60, 791–794 (1990). https://doi.org/10.1007/BF02399871
Issue Date:
DOI: https://doi.org/10.1007/BF02399871