Quantification of hydrochloric acid and particulate deposition resulting from space shuttle launches at John F. Kennedy space center, Florida, USA

Abstract

Observations of damage to vegetation, acute reductions in surface water pH, and kills of small fish prompted the Biomedical Operations and Research Office at the John F. Kennedy Space Center to initiate intensive environmental evaluations of possible acute and long-term chronic impacts that may be produced by repeated launches of the space shuttle. An important step in this evaluation was the identification of deposition patterns and the quantification of ecosystem loading rates of exhaust constituents from the solid rocket motors (SRMs) in the area of the launch pad. These constituents are primarily aluminum oxide (Al₂O₃) and hydrochloric acid (HCl). During three launches of the space transportation system (STS-11, 13, and 14) up to 100 bulk deposition collectors, 83 mm in diameter containing 100 ml of deionized water, were deployed in a grid pattern covering 12.6 ha north of launch pad 39-A. Estimates of HCl and particulate deposition levels were made based on laboratory measurements of items entrained in the collectors. Captured particulates consisted of a variety of items including Al₂O₃, sand grains, sea shell fragments, paint chips, and other debris ablated from the launch pad surface by the initial thrust of the SRMs. Estimated ranges of HCl and particulate deposition in the study area were 0–127 g/m² and 0–246 g/m², respectively. Deposition patterns were highly influenced by wind speed and direction. These measurements indicate that, under certain meteorological conditions, up to 7.1 × 10³ kg of particulates and 3.4 × 10³ kg of HCl can be deposited to the near-field environment beyond the launch pad perimeter fence.