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Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K

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Abstract

Gamma-irradiated at 77 K 1,4-dioxane and morpholine have been studied by ESR-spectroscopy. C-O bond dissociation is the main process in the γ-radiolysis of 1,4-dioxane and a significant contribution of −CH−CH=O radicals to the experimental spectrum is observed. Both H-atom abstraction and the cleavage of the ring seems to occur at low temperature γ-radiolysis of morpholine. The paths of formation of intermediates in cyclic ethers γ-irradiated at 77 K are discussed.

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  1. Karpov Institute of Physical Chemistry, ul. Vorontsovo Pole, 10, 103064, Moscow, Russia

    S. V. Nesterov

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  1. S. V. Nesterov
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Nesterov, S.V. Influence of heteroatom nature on the paths of formation of intermediates in gamma-irradiated cyclic ethers at 77 K. J Radioanal Nucl Chem 230, 273–276 (1998). https://doi.org/10.1007/BF02387478

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  • DOI: https://doi.org/10.1007/BF02387478

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