Abstract
The preparation and characterization of PVC-PMMA-LiBF4/LiAsF6-DBP composite polymer electrolytes for different concentrations of ZrO2 have been investigated. FTIR studies indicate complex formation between the polymers, salt and plasticizer. The electrical conductivity values measured by ac impedance spectroscopy were found to depend upon the ZrO2 concentration. The temperature dependence of the conductivity of the polymer films seems to obey the VTF relation. The conductivity values are presented and the results are discussed.
Similar content being viewed by others
6. References
C.C. Liang, J. Electrochem. Soc.120, 1289 (1973).
J. Maier, in: Superionic Solids and Solid Electrolytes, (A.L. Lasker and S. Chandra, Eds.) Academic Press, San Diego, 1989, pp. 132.
J.B. Wagner, Jr, in: High Conductivity Solid Ionic Conductors, (T. Takahashi, Ed.) World Scientific, Singapore, 1989, pp. 146.
J.R. MacCallum and C.A. Vincent, Eds., Polymer Electrolyte Reviews, Elsevier, New York, 1987 and 1989, Vols. I and II.
N. Munichandraiah, I.G. Scanlon, R.A. Marsh, B. Kumar and A.K. Sircar, Abstract 32, pp. 49, The Electrochem. Soc. Extended Abstracts Vol. 93-I, Honolulu, HI, 1993, May 16–21.
F. Capeano, F. Croce and B. Scrosati, J. Electrochem. Soc.138, 1918 (1991).
B. Kumar, J.D. Schaffer, N. Munichandraiah and P.T. Weissman, Power Sources 14 (A. Attewell and T. Keily, Eds.) International Power Sources, Symposium Committee, Surrey, UK, 1993, pp. 121.
W. Wieczorek, K. Such, H. Wycislik and J. Plocharski, Solid State Ionics36, 255 (1989).
F. Croce, S. Panero and B. Scrosati, Mater. Res. Soc. Symp. Proc.210, 179 (1991).
H.Y. Sun, H.J. Sohn, O. Yamamoto, Y. Takeda and N. Imanish, J. Electrochem. Soc.146, 1672 (1991).
M. Armand, Solid State Ionics69, 309 (1994).
Y. Aihara, M. Kodama, K. Nakahara, H. Okise and K. Marata, J. Power Sources65, 143 (1997).
Y. Ito, K. Kanehori, K. Miyauchi and T. Kudo, J. Mater. Sci.22, 1845 (1987).
J. Kelly, J.R. Owen and B.C.H. Steele, J. Electroanal. Chem.168, 467 (1984).
J. Kelly, J.R. Owen and B.C.H. Steele, J. Power Sources14, 13 (1985).
J. Przyluski and W. Wieczorek, Solid State Ionics36, 165 (1989).
M. Alamgir and K. Abraham, J. Electrochem. Soc.140, L96 (1993).
M. Sukeshini, A. Nishimoto and M. Watanabe, Solid State Ionics86, 385 (1996).
G.B. Appetecchi, F. Croce and B. Scrosati, Electrochim. Acta40, 991 (1995).
H.J. Rhoo, H.T. Jung, K. Park and T.S. Hwang, Electrochim. Acta42, 1571 (1997).
D.L. Vien, N.B. Colthup, W.G. Fateley and J.G. Grasselli, Infrared and Raman Characteristic Frequencies of Organic Molecules, Academic Press, Inc., New York, 1991, pp. 85.
M.B. Armand, J.M. Chabagno and M.J. Duclot, in: Fast -Ion Transport in Solids (P. Vashishta, J.N. Mundy and G. Shenoy, Eds.) North-Holland, Amsterdam, 1979, pp. 131.
M.L. Williams, R.F. Landell and J.D. Ferry, J. Am. Chem. Soc.77, 3701 (1955).
Y. Okamoto, T.F. Yeh, H.S. Lee and T.A. Skotheimk J. Polym. Sci. Part A, Polym. Chem.31, 2573 (1993).
H. Vogel, Phys. Z.22, 645 (1922).
V.G. Tamman and H. Hesse, Z. Anorg. Allg. Chem. 19, 245 (1926).
G.S. Fulcher, J. Am. Ceram. Soc.8, 339 (1925).
J. Plocharshi and W. Wieczorek, Solid State Ionics28, 979 (1988).
J. Przyluski, K. Such, H. Wycishik and W. Wieczorek, Synth. Met.35, 241 (1990).
W. Wieczorek, Mater. Sci. Eng. B15, 108 (1992).
A. Chandra, P.C. Srivastava and S. Chandra, J. Mater. Sci.30, 3633 (1995).
J. Plocharski, W. Wieczorek, J. Przyluski and K. Such, Appl. Phys. A49, 55 (1989).
N. Munichandraiah, L.G. Scanlon, R.A. Marsh, B. Kumar and A.K. Sircar, J. Appl. Electrochem.25, 857 (1995).
B. Kumar and L.G. Scanlon, J. Power Sources52, 261 (1994).
N. Munichandraiah, L.G. Scanlon, R.A. Marsh, B. Kumar and A.K. Sircar, J. Appl. Electrochem.24, 1066 (1994).
J. Przyluski, M. Sickierski and W. Wieczorek, Electrochim. Acta40, 2101 (1995).
B.K. Choi, Y.W. Kim and K.H. Shiv, J. Power Sources68, 357 (1997).
B. Kumar, J.D. Schaffer, N. Munichandraiah and L.G. Scanlon, J. Power Sources47, 63 (1994).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rajendran, S., Uma, T. Effect of ceramic oxide on PVC-PMMA hybrid polymer electrolytes. Ionics 6, 288–293 (2000). https://doi.org/10.1007/BF02374079
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02374079