Skip to main content
SpringerLink
Log in

Two-dimensional spin freezing in Y1−z Ca z Ba2Cu3−x Fe x O7

  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Hyperfine electric and magnetic interactions in Y1−z Ca z Ba2Cu3−x Fe x O6+y compounds have been studied for different rates of Fe and Ca substitution (x=0.09 and 0.24;z=0.24;y=0−1) by57Fe Mössbauer spectroscopy of powder samples obtained by different thermal treatments. Calculations of the Fe3+ EFG tensor have been performed for different coordination polyhedra in Cu1 and Cu2 sites. Variations of the direction, amplitude and of the sign of the principal component of the EFG are reported versus the iron displacement from the ideal Cu sites inside the pyramidal and tetrahedral coordination polyhedra. Calculated ΔE Q and η values are compared with the experimental ones. For the Cu2 site, faithfully probed in both oxygen-depleted and oxygen-saturated samples by fairly large fraction of residing iron atoms, the mutual orientations of the axes of the principal EFG component and that of easiest magnetization are deduced from interrelations between quadrupole parameters for paramagnetic quadrupolar and magnetic Zeeman Mössbauer spectra. In the desoxygenated samples, the coexistence of a long range 2D antiferromagnetic order and of a spin-glass order has been evidenced. For the oxygen-saturated samples, the two-dimensional spin-glass order is observed belowT f =10 K. The Mössbauer spectra under applied fields at 4.2 K show an easy polarization of the spins in the Cu2 sites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Tamaki, T. Komai, A. Ito, Y. Maeno and T. Fujita, Solid State Commun. 65 (1988) 43.

    Article  Google Scholar 

  2. T. Tamaki, M. Nishizawa, A. Ito and F. Fujita, Hyp. Int. 55 (1990) 1393.

    Google Scholar 

  3. S.C. Bhargava, J.L. Dormann, J. Jové, O. Gorochov, C. Djega-Mariadassou, H. Pankowska and R. Suryanarayanan, J. Phys. C 21 (1988) L905.

    Google Scholar 

  4. Q.A. Pankhurst, A.H. Morrish, M. Raudsepp and X.Z. Zhou, J. Phys. C 21 (1988) L7.

    Google Scholar 

  5. V.A. Andrianov, O.L. Anisimova, M.G. Kozin, A.Yu. Pentin, S.I. Semenov, V.S. Shpinel, L.I. Leonyuk, V.V. Moshchalkov and S.V. Red'ko, Physica C 166 (1990) 248.

    Article  ADS  Google Scholar 

  6. S.C. Bhargava, J.L. Dormann, S. Sayouri, J. Jové, G. Prifits, H. Pankowska, O. Gorochov and R. Suryanarayanan, Bull. Mater. Sci. 14 (1991) 687.

    Google Scholar 

  7. S. Suharan, C.E. Johnson, Q.A. Pankhurst and M.F. Thomas, Solid State Commun. 78 (1991) 897.

    Article  Google Scholar 

  8. W. Peng, C.W. Kimball and B.D. Dunlap, Physica C 169 (1990) 23.

    Article  ADS  Google Scholar 

  9. Y. Liang, B. Dabrowski, C.W. Kimball, W. Peng and B.D. Dunlap, Physica C 190 (1992) 415.

    ADS  Google Scholar 

  10. I. Felner, I. Nowik, E.R. Bauminger, D. Hechel and U. Yaron, Phys. Rev. Lett. 65 (1990) 1945.

    Article  ADS  Google Scholar 

  11. H. Tang, Z.Q. Qiu and J.C. Walker, J. Appl. Phys. 69 (1991) 5379.

    ADS  Google Scholar 

  12. I.S. Lyubutin, V.G. Terziev, T.V. Dmitrieva, A.M. Balagurov and S. Nasu, Physica C 195 (1992) 383.

    Article  ADS  Google Scholar 

  13. E. Suard, V. Caignaert, A. Maignan and B. Raveau, Physica C 182 (1991) 219.

    Article  ADS  Google Scholar 

  14. M.G. Smith, R.D. Taylor and H. Oesterreicher, J. Appl. Phys. 69 (1991) 4894.

    ADS  Google Scholar 

  15. I. Mirebeau, M. Hennion, G. Goddens, T.E. Phillips and K. Moorjan, Europhys. Lett. 9 (1989) 181.

    ADS  Google Scholar 

  16. S. Katano, T. Matsumot, A. Matsushita, T. Hatano and S. Funahashi, Phys. Rev. B (1990) 2009.

  17. I. Mirebeau, M. Hennion, J. Dianoux, V. Caignaert and K. Moorjani, J. Appl. Phys. 67 (1990) 4521.

    ADS  Google Scholar 

  18. S. Katsuyama, Y. Ueda and K. Kosuge, Physica C 165 (1990) 404.

    Article  ADS  Google Scholar 

  19. A. Rykov, V. Caignaert, N. Nguyen, A. Maignan, E. Suard and B. Raveau, Physica C 205 (1993) 63.

    Article  ADS  Google Scholar 

  20. Yu.T. Pavlyuhin, N.G. Hainovsky, Y.Y. Medikov and A.I. Rykov, Pramana J. Phys. 31 (1988) L445.

    Google Scholar 

  21. Yu.T. Pavlyuhin, N.G. Hainovsky, Ya.Ya. Medikov and A.I. Rykov, Int. J. Mod. Phys. B 3 (1989) 711.

    ADS  Google Scholar 

  22. P. Blaha, K. Schwarz and P. Herzig, Phys. Rev. Lett. 54 (1989) 1192.

    ADS  Google Scholar 

  23. C. Ambrosch-Draxl, P. Blaha and K. Schwarz, J. Phys. Condens. Matter 1 (1989) 4491.

    Article  ADS  Google Scholar 

  24. F. Hartmann-Boutron, C. Meyer, Y. Gros, P. Strobel and J.L. Tholence, Hyp. Int. 55 (1990) 1293.

    Google Scholar 

  25. G.M. Bancroft and R.H. Platt, in:Advances in Inorganic Chemistry and Radiochemistry, Vol. 15, eds. H.J. Emeléus and A.G. Sharpe (Academic Press, New York, 1992) p. 59.

    Google Scholar 

  26. M.G. Smith, R.D. Taylor and H. Oesterreicher, Phys. Rev. B 42 (1990) 4202.

    ADS  Google Scholar 

  27. C.H. Pennington, D.J. Durand, C.P. Slichter, J.P. Rice, E.D. Bukowski and D.M. Ginsberg, Phys. Rev. B 39 (1989) 2902.

    ADS  Google Scholar 

  28. R.M. Sternheimer, Phys. Rev. 130 (1963) 1423.

    Article  ADS  Google Scholar 

  29. P. Gütlich, R. Link, A. Trautwein,Mössbauer Spectroscopy and Transition Metal Chemistry (Springer, Berlin, 1978).

    Google Scholar 

  30. N.N. Greenwood and T.C. Gibbs,Mössbauer Spectroscopy (Chapman and Hall, London, 1971).

    Google Scholar 

  31. K.J. Duff, K.C. Mishra and T.P. Das, Phys. Rev. Lett. 46 (1981) 1611.

    Article  ADS  Google Scholar 

  32. A. Nath, Z. Homonnay, S.D. Tyagi, Y. Wei, G.W. Jang and C.C. Chan, Physica C 171 (1990) 406.

    Article  ADS  Google Scholar 

  33. T. Okada, M.D. Lan, J.Z. Liu, R.N. Shelton, T. Matsumoto and K. Asai, Physica C 185–189 (1991) 783.

    Google Scholar 

  34. R.A. Brand, Ch. Sauer, H. Lütgemeier, P.M. Meuffels and W. Zinn, Hyp. Int. 55 (1990) 1229.

    Google Scholar 

  35. V. Chechersky and A. Nath, Hyp. Int. 72 (1992) 173.

    Google Scholar 

  36. M. Eibschütz and M.E. Lines, Phys. Rev. B 25 (1982) 4256.

    Article  ADS  Google Scholar 

  37. E.R. Bauminger, M. Kowitt, I. Felner and I. Nowik, Solid State Commun. 65 (1988) 123.

    Article  Google Scholar 

  38. S. Nagy, Y. Wei and A. Nath, Hyp. Int. 66 (1991) 381.

    Google Scholar 

  39. J. Dengler, G. Ritter, G. Saemann-Ischenko, B. Roas, L. Schultz, B. Molnar, D.L. Nagy and I.S. Szücs, Hyp. Int. 55 (1990) 1267.

    Google Scholar 

  40. B.D. Dunlap, J.D. Jørgensen, C. Segre, A.E. Dwight, J.L. Matykiewicz, H. Lee, W. Peng and C.W. Kimball, Physica C 158 (1989) 397.

    Article  ADS  Google Scholar 

  41. P.F. Miceli, J.M. Tarascon, L.H. Greene, P. Barboux, M. Giroud, D.A. Neumann, J.J. Rhyne, L.F. Schneemeyer and J.J. Waszczakn, Phys. Rev. B 38 (1988) 9209.

    Article  ADS  Google Scholar 

  42. J.L. Garcia-Munoz, J. Rodrigues-Carvajal, S.H. Kilcoyne, C.J. Boardman and R. Cywinski, J. Magn. Magn. Mater. 104–107 (1992) 555.

    Google Scholar 

  43. P. Zolliker, D.E. Cox, J.M. Tranquada and G. Shirane, Phys. Rev. B 38 (1988) 6575.

    Article  ADS  Google Scholar 

  44. I. Mirebeau, C. Bellouard, M. Hennion, G. Jehanno, V. Caignaert, A.J. Dianoux, T.E. Phillips and K. Moorjani, Physica C 184 (1991) 299.

    Article  ADS  Google Scholar 

  45. I.S. Lyubutin, V.G. Terziev, S.V. Luchko, A.Ya. Shapiro, A.M. Balagurov and G.A. Bonch-Osmolovskiy, Physica C 199 (1992) 296.

    Article  ADS  Google Scholar 

  46. A. Rykov, V. Caignaert, N. Nguyen and B. Raveau, unpublished.

  47. E. Baggio Saitovitch, F.J. Litterst, I. Souza Azevedo and R.B. Scorzelli, Hyp. Int. 50 (1989) 529.

    Google Scholar 

  48. K. Binder and A.P. Young, Rev. Mod. Phys. 58 (1986) 801.

    Article  ADS  Google Scholar 

  49. M. Gabay and G. Toulouse, Phys. Rev. Lett. 47 (1981) 201.

    Article  ADS  Google Scholar 

  50. P.W. Anderson, J. Appl. Phys. 49 (1978) 1599.

    ADS  Google Scholar 

  51. J.M. Kosterlitz and D.J. Thouless, J. Phys. C 6 (1973) 1181.

    Article  ADS  Google Scholar 

  52. H. Ren and D.H. Ryan, J. Appl. Phys. 70 (1991) 5837.

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire CRISMAT, CNRS URA 1318, ISMRA, Université de Caen, 14050, Caen Cedex, France

    A. Rykov, A. Ducouret, N. Nguyen, V. Caignaert, F. Studer & B. Raveau

Authors
  1. A. Rykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Ducouret
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. Nguyen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. Caignaert
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. Studer
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. Raveau
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rykov, A., Ducouret, A., Nguyen, N. et al. Two-dimensional spin freezing in Y1−z Ca z Ba2Cu3−x Fe x O7 . Hyperfine Interact 77, 277–299 (1993). https://doi.org/10.1007/BF02320318

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02320318

Keywords

Search

Navigation