Skip to main content
SpringerLink
Log in

How to count strong adsorption sites by gas chromatography?

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

A simple gas chromatographic method is presented for the determination of the quantity of the strongest adsorption sites on an adsorbent's surface. The method consists of the blockage of the sites with quasi-irreversibly adsorbed, known amount of a strongly interacting compound and subsequent measuring of the retention of a hydrocarbon during the presence of the blocking compound in the column. Heterogeneity of chromatographic grade silicas is investigated with this method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Tanabe, Solid Acids and Bases. Their Catalytic Properties, Kodansha, Tokyo, Academic Press, New York, 1970; Russian edition: Izd. Mir, Moscow, 1973.

    Google Scholar 

  2. T. Paryjczak, Gas Chromatography in Adsorption and Catalysis, Ellis Horwood Ltd Publishers Chichester, 1986.

    Google Scholar 

  3. P. E. Eberly, J. Phys. Chem.,65, 68, 1261 (1961).

    CAS  Google Scholar 

  4. A. Waksmundzki, W. Rudziński, Z. Suprynowicz, R. Leboda, M. M. Lasoń, J. Chromatogr.,92, 9 (1974).

    Article  CAS  Google Scholar 

  5. W. Rudziński, A. Waksmundzki, R. Leboda, Z. Suprynowicz, M. Lasoń, J. Chromatogr.,92, 25 (1974).

    Google Scholar 

  6. R. Leboda, S. Sokolowski, J. Rynkowski, T. Paryjczak, J. Chromatogr.138, 309 (1977).

    Article  CAS  Google Scholar 

  7. J. Gawdzik, Z. Suprynowicz, M. Jaroniec, J. Chromatogr.131, 7 (1977).

    CAS  Google Scholar 

  8. W. T. Cooper, J. M. Hayes, J. Chromatogr.314, 111 (1984).

    Article  CAS  Google Scholar 

  9. J. Nawrocki, J. Chromatogr.362, 117 (1986).

    Article  CAS  Google Scholar 

  10. J. Nawrocki J. Chromatogr.391, 266 (1987).

    Article  CAS  Google Scholar 

  11. J. Nawrocki, J. Chromatogr.407, 171 (1987).

    Article  CAS  Google Scholar 

  12. M. L. Hair, W. Hertl, J. Phys. Chem.,73, 4269 (1969).

    CAS  Google Scholar 

  13. G. Curthoys, V. Ya. Davydov, A. V. Kiselev, S. A. Kiselev, B. V. Kuznetzov, J. Colloid Interface Sci48, 58 (1974).

    Article  CAS  Google Scholar 

  14. J. Nawrocki — to be published.

  15. K. K. Unger, Porous Silica, Elsevier, Amsterdam, 1979.

    Google Scholar 

  16. A. V. Kiselev, Ya. Yashin, Gas Adsorption Chromatography, PWN, Warsaw, 1969 (in Polish).

    Google Scholar 

  17. D. M. Marshall, C. L. Cole, D. E. Connolly, J. Chromatogr.361, 71 (1986).

    CAS  Google Scholar 

  18. A. V. Kiselev, Quarter. Rev.15, 99 (1961).

    CAS  Google Scholar 

  19. J. A. Cusumano, M. J. Low, J. Phys. Chem.74, 792 (1970).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, A. Mickiewicz University, ul Grunwaldzka 6, 60-780, Poznań, Poland

    J. Nawrocki

Authors
  1. J. Nawrocki
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nawrocki, J. How to count strong adsorption sites by gas chromatography?. Chromatographia 23, 722–726 (1987). https://doi.org/10.1007/BF02312663

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02312663

Key Words

Search

Navigation