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Seed oil extraction with supercritical carbon dioxide modified with pentane

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Summary

Soybean, wheat germ, sunflower and peanut oils were extracted with supercritical carbon dioxide modified with pentane. The extractions were optimized by chemometric methods using as frontier limits; supercritical pressures of 50 to 150 atm, supercritical temperatures of 60 to 100°C and extraction times of 5 to 15 min. The oils extracted with CO2/pentane were compared to those obtained through conventional extraction methods using hexane.

Analysis of the fatty acid methyl esters and tocopherols and color intensity measurements carried out for the characterization of the oils extracted by CO2/pentane gave similar results to oils Soxhlet extracted with hexane.

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References

  1. J. P. Friedrich, G. R. List, J. Agric. Food Chem.30, 192 (1982).

    Google Scholar 

  2. G. R. List, J. W. King, J. H. Johnson, K. Warner, T. L. Mounts, J. Am. Oil Chem. Soc.70, 473 (1993).

    Google Scholar 

  3. S. L. Taylor, J. W. King, G. R. List, J. Am. Oil Chem. Soc.70, 437 (1993).

    Google Scholar 

  4. J. P. Friendrich, G. R. List, G. F. Spencer, “Proc. 7 th. Int. Conf. on jojoba and its Uses”, Ed. A. R. Baldwin, 1988, p. 165.

  5. G. R. List, J. P. Friedrich, J. Pominski, J. Am. Oil. Chem. Soc.61, 1847 (1984).

    Google Scholar 

  6. F. Favati, J. W. King, M. Mazzanti, J. Am. Oil Chem. Soc.68, 422 (1991).

    Google Scholar 

  7. M. Gonçalves, A. M. P. Vasconcelos, E. J. Gomes De Azevedo, H. J. Chaves Das Neves, J. Am. Oil Chem. Soc.68, 474 (1991).

    Google Scholar 

  8. L. Brunetti, A. Daghetta, E. Fedeli, I. Kikic, L. Zanderighi, J. Am. Oil Chem. Soc.66, 1989).

  9. M. L. Lee, K. E. Markides “Analytical Supercritical Fluid Chromatography and Extraction”, Chromatography Conferences Provo, 1990.

  10. V. Berry, LC-GC8, 732 (1990).

    Google Scholar 

  11. M. Taniguchi, T. Tsuji, M. Shibata, T. Kobayashi, Agric. Biol. Chem.49, 2367 (1985).

    Google Scholar 

  12. R. Eggers, U. Sievers, W. Stein, J. Am. Oil Chem. Soc.62, 1222 (1985).

    Google Scholar 

  13. F. M. Lanças, M. E. C. Queiroz, I. E. Silva, submitted to Anal. Chem. Acta (1994).

  14. F. M. Lanças, M. S. Galhiane, M. A. Barbirato, Chromatographia39, 11 (1994).

    Google Scholar 

  15. J. H. Vilegas, F. M. Lanças, Flavour and Fragrance9, 39 (1994).

    Google Scholar 

  16. S. R. Sargenti, F. M. Lanças, J. Chromatogr. A.667, 213 (1994).

    Google Scholar 

  17. J. H. Vilegas, F. M. Lanças, W. Vilegas, G. L. Pozetti, Phytochem. Anal.4, 230 (1993).

    Google Scholar 

  18. F. M. Lanças, B. S. De Martins, M. H. R. Da Matta, J. High Resol. Chromatogr.13, 838 (1990).

    Google Scholar 

  19. G. E. P. Box, W. G. Hunter, S. Hunter, “Statistics for Experiments”. John Wiley and Sons, New York, 1978.

    Google Scholar 

  20. L. Hartman, R. C. A. Lago, Lab. Pract.7, 475 (1973).

    Google Scholar 

  21. F. M. Lanças, N. R. Antoniosi Filho, proceeding of the Fifteenth International Symposium on Capillary Chromatography, Riva del Garda, Italy, 1993.

  22. M. I. Santoro, J. F. Magalhães, E. R. M. Hackmann, J. Assoc. Anal. Chem.,65, 619 (1982).

    Google Scholar 

  23. N. K. Andrikopoulos, H. Brueschweiler, H. Felber, Ch. Taeschler, J. Am. Oil Chem. Soc.68, 359 (1991).

    Google Scholar 

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Lanças, F.M., Queiroz, M.E.C. & de Silva, I.C.E. Seed oil extraction with supercritical carbon dioxide modified with pentane. Chromatographia 39, 687–692 (1994). https://doi.org/10.1007/BF02274584

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  • DOI: https://doi.org/10.1007/BF02274584

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