Abstract
Hydromethylamination of 1,3-diaryl-3-(2-oxocyclohexyl)propan-1-ones produces N-methyl-2,4-diaryldecahydroquinolines with cis-fused hetero- and carbocycles that are stabilized in the A conformation. The reaction involves Δ2,3,9,10 intermediates and their subsequent reduction.
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Additional information
For No. 17, see [1].
N. G. Chernyshevskii, Saratov State University, Saratov 410026, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 929–933, July, 1999.
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Nikolaeva, T.G., Petrova, N.V. & Kriven'ko, A.P. Saturated nitrogen-containing heterocycles. 18. Catalytic synthesis and formation mechanism of substitutedcis-decahydroquinolines and their isologues. Chem Heterocycl Compd 35, 813–817 (1999). https://doi.org/10.1007/BF02252106
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DOI: https://doi.org/10.1007/BF02252106