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Exponential kinetic equation for the process of hypochlorite treatment of pulps

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Abstract

An explanation is proposed for the exponential rate equation obtained in a kinetic study of the interaction between calcium hypochlorite and different kinds of commucial pulp. It has been confirmed that this kinetic equation describes the reaction of delignification of pulp. The importance of the entropy factor has been explained with the net-structure of lignin and its modifications.

Abstract

Предлагается обьяснение для экспоненциального уравнения скорости, полученного в кинетическом исследовании взаимодействий между гипохлоритом кальция и различными видами целлюлозной пульпы. Было найдено, что это кинетическое уравнение описывает реакцию делигнификации пульпы. Важность энтропийного фактора объясняается на основе сетчатой структуры лигнина и его модификаций.

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Authors and Affiliations

  1. Department of Physical Chemistry, Institute of Chemical Technology, Sofia, Bulgaria

    St. Veleva

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  1. St. Veleva
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St. Veleva Exponential kinetic equation for the process of hypochlorite treatment of pulps. React Kinet Catal Lett 3, 125–130 (1975). https://doi.org/10.1007/BF02187503

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  • DOI: https://doi.org/10.1007/BF02187503

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