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Transannular reaction between ester and amide groups. Formation of a cyclol peptide derivative

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Zusammenfassung

Es wird die Synthese des Laktons (III) von Glykokoll-L-leucyl-L-prolin (IV) beschrieben. Spektroskopische Untersuchungen zeigen, dass das Lakton (III) eine durch Säure katalysierte transannulare Reaktion unter Bildung des Cyclol-Peptid-Derivats (II) durchläuft.

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Authors and Affiliations

  1. Robert Robinson Laboratories, University of Liverpool, England

    R. C. Sheppard

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  1. R. C. Sheppard
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Sheppard, R.C. Transannular reaction between ester and amide groups. Formation of a cyclol peptide derivative. Experientia 19, 125–126 (1963). https://doi.org/10.1007/BF02171584

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