Zusammenfassung
Ausgehend von neueren Anschauungen über die Stabilität verschiedener Konstellationen (conformations) monozyklischer Ringverbindungen wurden die Verhältnisse bei perhydrierten polyzyklischen Verbindungen diskutiert. Daraus konnten gewisse Regeln über die relative Stabilität der einzelnen Stereoisomeren abgeleitet werden.
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Literatur
D. H. R. Barton, Exper.6, 312 (1950).
For a summary of evidence see ref. 2.
The stereochemical method of representing formulas employed here is that of Linstead [seeR. P. Linstead, Chemistry and Industry56, 510 (1937), andR. P. Linstead, W. E. Doering, S. B. Davis, P. Levine, andR. Whetstone, J. Amer. Chem. Soc.64, 1985 (1942)], in which hydrogen atoms above the plane of the ring are represented by dots.
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R. P. Linstead, R. R. Whetstone, andP. Levine, J. Amer. Chem. Soc.64, 2014 (1942).
R. P. Linstead andR. R. Whetstone, J. Chem. Soc.,1950, 1428.
For a summary of evidence see ref. 2, p. 315.
J. W. Cook, N. A. McGinnis, andS. Mitchell, J. Chem. Soc.1944, 286.
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Johnson, W.S. The relative stability of stereoisomeric forms of fused ring systems. Experientia 7, 315–317 (1951). https://doi.org/10.1007/BF02150564
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DOI: https://doi.org/10.1007/BF02150564