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Discrimination of the mechanisms of cooxidation of arylalkanes and alkylamines

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Abstract

Numerical analysis of experimental data on the cooxidation of arylalkanes and alkylamines indicates a chain propagation and interruption mechanism with the participation of amine cation radicals. The steps corresponding to the classical cooxidation mechanism are excessive in this experiment.

Abstract

Численный аналцз экперименталыных данных процесса соокисления арилалканов и алкиламинов указывает на механизм продолжения и обрыва цепей с участием катионг адикалов амина. Стадии, отвечающие только классическому сопряженному окислению, в рамках данного эксперимента избыточны.

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Authors and Affiliations

  1. Institute of Chemistry, Institute of Petrochemical Technology, Ufa, USSR

    I. R. Akhunov & S. I. Spivak

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  1. I. R. Akhunov
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  2. S. I. Spivak
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Akhunov, I.R., Spivak, S.I. Discrimination of the mechanisms of cooxidation of arylalkanes and alkylamines. React Kinet Catal Lett 24, 305–308 (1984). https://doi.org/10.1007/BF02093447

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  • DOI: https://doi.org/10.1007/BF02093447

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