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Transfer hydrogenation of phenanthrene in the presence of boron modified alumina or silica-alumina

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Abstract

Reactions of phenanthrene with hydrogen donors carried out in the presence of boron trifluoride etherate modified catalysts: silica, alumina or silica-alumina have been studied. Di-, tetra- and octahydrophenanthrenes as well as some bicyclic hydrocarbons were the reactions products. Their yields were strongly influenced by hydrogen donor polarity.

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Authors and Affiliations

  1. Department of Chemistry, Warsaw Technical University, ul. Koszykowa 75, 00-662, Warszawa, Poland

    Piotr Winiarek, Elżbieta Fedoryńska & Piotr Cholewiński

Authors
  1. Piotr Winiarek
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  2. Elżbieta Fedoryńska
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  3. Piotr Cholewiński
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Winiarek, P., Fedoryńska, E. & Cholewiński, P. Transfer hydrogenation of phenanthrene in the presence of boron modified alumina or silica-alumina. React Kinet Catal Lett 55, 191–197 (1995). https://doi.org/10.1007/BF02075850

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  • DOI: https://doi.org/10.1007/BF02075850

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