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Possible chain mechanism of oxygen atom transfer

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Abstract

A chain mechanism is suggested for reactions in polar media which proceed according to the general scheme

$$LO + B \to L + BO$$

The mechanism involves one-electron oxidation of LO, further reactions of\(LO^{\mathop + \limits_. } \) with O+ or O atom transfer and the electron transfer from LO to\(BO^{\mathop + \limits_. } \) or to\(L^{\mathop + \limits_. } \). Some examples of possible reactions are discussed.

Abstract

Предложен цепной механизм для реакций в полярных средах, протекающих по общей схеме:

$$LO + B ---- > L + BO$$

Механизм включает одно-электронное окисление LO, дальнейшие реакции\(LO^{\mathop + \limits_. } \) с переносом O+ или атома O и перенос электрона от LO к\(BO^{\mathop + \limits_. } \) или\(L^{\mathop + \limits_. } \). Обсуждаются примеры возможных реакций.

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  1. Institute of Chemical Physics, 142432, Chernogolovka, USSR

    A. E. Shilov

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  1. A. E. Shilov
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Shilov, A.E. Possible chain mechanism of oxygen atom transfer. React Kinet Catal Lett 41, 223–226 (1990). https://doi.org/10.1007/BF02075508

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  • DOI: https://doi.org/10.1007/BF02075508

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