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UV-spectroscopic studies on the interaction of triethyl aluminium with cobalt and aluminium acetylacetonates

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Abstract

The Al(acac)3/Et2Al(acac) ratio depends on the Al/Co and the solvent. The solvent contains Et2Al(acac) as a dimer, which is stabilized in the presence of Co(O) and arenes. The role of Et2Al(acac) dimer in the formation of active Co(O) complexes is discussed.

Abstract

Показано, что соотношение Al(acac)3/Et2 Al(acac) зависит от Al/Co и природы растворителя. Установлено существование (Et2Al(acac) в састворе в форме димера и стабилизация его в присутствии Co(O) и аренов. Обсуждается роль димера Et2Al(acac) в образовании активных комплексов Co(O).

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References

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Authors and Affiliations

  1. Institute of Petroleum and Coal Synthesis, Zhdanov State University, Irkutsk, USSR

    G. V. Ratovskii, T. V. Dmitrieva, L. O. Nindakova & F. K. Shmidt

Authors
  1. G. V. Ratovskii
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  2. T. V. Dmitrieva
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  3. L. O. Nindakova
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  4. F. K. Shmidt
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Ratovskii, G.V., Dmitrieva, T.V., Nindakova, L.O. et al. UV-spectroscopic studies on the interaction of triethyl aluminium with cobalt and aluminium acetylacetonates. React Kinet Catal Lett 11, 121–124 (1979). https://doi.org/10.1007/BF02074198

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  • DOI: https://doi.org/10.1007/BF02074198

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