Skip to main content
SpringerLink
Log in

Kinetics of oxidation of octacyanomolybdate(V) ion by thiosulfate

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The oxidation of thiosulfate by octacyanomolybdate(V) in the pH range of 4,0 to 5,1 is catalyzed by alkali metal ions and shows first order dependence on the concentrations of thiosulfate, octacyanomolybdate(V) and alkali metal ions and is independent of the hydrogen ion concentration. A mechanism for the reaction is proposed.

Abstract

Окисление тиосульфата октацианомолибдатом(V) в области pH=4,0–5,1 катлизируется ионами щелочных металлов. Была найдена зависимость первого порядка от концентрации тиосульфата, октацианомлибата(V) и ионов щелочных металлов. Скорость не зависит от концентрции водородных ионов. Предлагается механизм реакции.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. E. Howlett, B. L. Wedzicha Inorg. Chim. Acta.,18, 133 (1976).

    Google Scholar 

  2. J. G. Leipoldt, L. D. C. Bok, C. R. Dennis: J. Inorg. Nucl. Chem.,38, 1655 (1976).

    Google Scholar 

  3. L. D. C. Bok, J. G. Leipoldt, S. S. Basson: Z. anorg. allg. Chem.,415, 81 (1975).

    Google Scholar 

  4. V. K. Jindal, M. C. Agrawal, S. P. Mushran: J. Inorg. Nucl. Chem.,33, 2469 (1971).

    Google Scholar 

  5. V. N. Singh, M. C. Gangwar, B. B. L. Saxena M. P. Singh: Can. J. Chem.,47, 1051 (1969).

    Google Scholar 

  6. J. H. Karchem, Ed.: The Analytical Chemistry of Sulfur and its Compounds, Part 1, p. 240. Wiley, New York 1970.

    Google Scholar 

  7. T. M. Kolthoff R. Belcher: Volumetric Analysis Vol. III, p. 296, 299, Intersienc New York 1957.

    Google Scholar 

  8. G. Nord, L. H. Skibsted, A. S. Halonin: Acta Chem. Scand.,A29, 505 (1975).

    Google Scholar 

  9. P. J. Cilliers: D. Sc. Thesis, 57 (1976), University of the Orange Free State, Bloemfontein, R.S.A.

  10. F. M. Page: J. Chem. Soc., 1719 (1953).

  11. P. Jain, F. Nandel: J. Chem. Soc. (Dalton), 949 (1977).

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa

    G. J. Lamprecht, J. G. Leipoldt, C. R. Dennis & S. S. Basson

Authors
  1. G. J. Lamprecht
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. G. Leipoldt
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. R. Dennis
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. S. Basson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lamprecht, G.J., Leipoldt, J.G., Dennis, C.R. et al. Kinetics of oxidation of octacyanomolybdate(V) ion by thiosulfate. React Kinet Catal Lett 13, 269–275 (1980). https://doi.org/10.1007/BF02068577

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02068577

Keywords

Search

Navigation