Skip to main content
SpringerLink
Log in

Characterization of the interaction of CO and H2 at the ZnO surface by adsorption microcalorimetry

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

CO and H2 are both chemisorbed by ZnO but H2 is more sensitive than CO to the surroundings of adsorption sites. When the two gases are coadsorbed, a strong interaction occurs, ascribed to the formation of a possible precursor in methanol synthesis.

Abstract

CO и H2 оба хемисорбируются на ZnO, но H2 является более чувствительным к окружению на адсорбционных, центрах, чем CO. Если оба газа соадсорбируются, то происходит сильное взаимодействие, приводящее к образованию возможного исходного продукта в синтезе метанола.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. S. Nagarjunan, M. V. C. Sastri, F. C. Kuriacose: J. Catal.,2, 223 (1963).

    Google Scholar 

  2. C. Aharoni, F. C. Tompkins: Trans. Faraday Soc.,66, 434 (1970).

    Google Scholar 

  3. F. Boccuzzi, E. Garrone, A. Zecchina, A. Bossi, M. Camia, J. Catal.51, 160 (978).

  4. C. H. Amberg, D. A. Seanor: Proc. 3rd Int. Congr. Cat., p. 450 (1965). C. H. Amberg, D. A. Seanor: J. Chem. Phys.,42, 2967 (1965).

  5. R. P. Eischens, W. A. Pleskins, M. J. D. Low: J. Catal.,1, 180 (1962).

    Google Scholar 

  6. C. C. Chang, R. J. Kokes: J. Amer. Chem. Soc.,93, 7107 (1971).

    Google Scholar 

  7. A. L. Dent, R. J. Kokes: J. Phys. Chem.,73, 3773 (1969).

    Google Scholar 

  8. D. Narayama, V. S. Subrahananyan, J. Lal, M. Mahannod Ali, V. Kesavulu: J. Phys. Chem.,74, 779 (1970).

    Google Scholar 

  9. A. Baranski, R. Cvetanovič: J. Phys. Chem.,75, 208 (1971).

    Google Scholar 

  10. A. Baranski, J. Galuszka: J. Catal.,44, 259 (1976).

    Google Scholar 

  11. F. Boccuzzi, E. Borello, A. Zecchina, A. Bossi, M. Camia: J. Catal.,51, 150 (1978).

    Google Scholar 

  12. G. Della Gatta, B. Fubini, G. Venturello: J. Chim. Phys.,70, 64 (1973).

    Google Scholar 

  13. B. Fubini: Rev. Gen. Therm.,18, (209), 297 (1979).

    Google Scholar 

  14. B. Fubini, E. Giamello, G. Della Gatta, G. Venturello: to be published.

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Generale ed Inorganica, Facolta di Farmacia, Universita di Torino, Via Pietro Giuria, 9, 10125, Torino, Italy

    E. Giamello & B. Fubini

Authors
  1. E. Giamello
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Fubini
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giamello, E., Fubini, B. Characterization of the interaction of CO and H2 at the ZnO surface by adsorption microcalorimetry. React Kinet Catal Lett 16, 355–358 (1981). https://doi.org/10.1007/BF02066590

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02066590

Keywords

Search

Navigation