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Mössbauer and X-ray study of rapidly quenched and mechanically alloyed Al-Fe alloys

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Abstract

Mössbauer spectroscopy and X-ray diffractometry were used to study the effect of the cooling rate as well as of the milling time on the structure of rapidly quenched Al-6.8% Fe, Al-0.5% Fe and mechanically alloyed Al-8% Fe alloys. The main phase of the rapidly quenched alloys was identified as Al m Fe besides Al6Fe andAlFe solid solutions. In the mechanically alloyed samples (with milling time between 1.5–43 hours), we have found α-Fe, AlFe solid solution and a third phase characterized by a doublet with Mössbauer parameters which are not so far from those of clusters inAlFe alloys. We have observed a continuous increase of the quantity ofAlFe solid solution, together with a significantly less increase of the third phase as a function of the milling time. Simultaneously, the quantity of alpha-iron has gradually decreased.

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Kuzmann, E., Vértes, A., Griger, Á. et al. Mössbauer and X-ray study of rapidly quenched and mechanically alloyed Al-Fe alloys. Hyperfine Interact 92, 943–947 (1994). https://doi.org/10.1007/BF02065716

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  • DOI: https://doi.org/10.1007/BF02065716

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