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Thiophene hydrogenolysis on NiS/SiO2 catalysts

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Abstract

NiS/SiO2 catalysts prepared through surface allyl complexes, are shown to be more active for thiophene hydrogenolysis than those obtained via silica impregnation by aqueous nickel nitrate. The increased activity is due to the higher dispersity of NiS prepared from its organometallic precursor.

Abstract

Нанесённые сульфидные никелевые катализаторы, приготовленные через стадию синтеза поверхностных аллильных комплексов, более активны в реакции гидрогенолиза тиофена, чем катализаторы, приготовленные пропиткой силикагеля водным раствором нитрата никеля. Это возрастанне активности связано с более высокой дисперсностяю нанесённого сульфида ннкеля “Металлоорганического” происхождения.

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References

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    V. A. Burmistrov, A. N. Startsev & Yu. I. Yermakov

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  1. V. A. Burmistrov
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  2. A. N. Startsev
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  3. Yu. I. Yermakov
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Burmistrov, V.A., Startsev, A.N. & Yermakov, Y.I. Thiophene hydrogenolysis on NiS/SiO2 catalysts. React Kinet Catal Lett 22, 107–111 (1983). https://doi.org/10.1007/BF02064815

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  • DOI: https://doi.org/10.1007/BF02064815

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