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Effect of support on dehydrogenation of methanol to methyl formate over Cu-containing catalysts prepared by ion exchange

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Abstract

Effect of supports such as SiO2, ZrO2 and TiO2 on the dehydrogenation of methanol were studied using Cu containing catalysts prepared by ion exchange. It was found that the catalytic activity, selectivity to methyl formate, and turnover frequency differ widely, depending on the support. Every catalyst showed a long life for the reaction.

Abstract

Влияние носителей, таких как SiO2, ZrO2 и TiO2 на дегидрирование метанола, исследовали на медных катализаторах, приготовленных ионо-обменным методом. Найдено, что каталитическая активность, селективность к метиловому эфиру муравьиной кислоты и число каталитических центров сильно зависят от природы носителя. Каждый катализатор обладает продолжительной жизнью в реакции.

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Authors and Affiliations

  1. Department of Industrial Chemistry, Faculty of Engineering, Chiba University, 260, Chiba, Japan

    T. Sodesawa

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  1. T. Sodesawa
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Sodesawa, T. Effect of support on dehydrogenation of methanol to methyl formate over Cu-containing catalysts prepared by ion exchange. React Kinet Catal Lett 32, 63–69 (1986). https://doi.org/10.1007/BF02063451

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  • DOI: https://doi.org/10.1007/BF02063451

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