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Reduction behavior of Cu−SiO2 catalyst prepared by ion exchange for selective dehydrogenation to produce methyl formate from methanol

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Abstract

Reducibility of Cu−SiO2 catalyst prepared by ion exchange method, being effective for selective dehydrogenation to produce methyl formate from methanol at lower temperatures, has been studied by a TPR technique. The results suggest that easier reduction leads to an increase of dispersity of Cu particles.

Abstract

Восстанавливаемость катализаторов, приготовленных с помощью ионо-обменного метода, эффективная для селективного дегидрирования метанола до метилового эфира муравьиной кислоты при низких температурах, изучена с помощью техники ТПВ. Результаты свидетельствуют о том, что чем легче восстановление, тем выше дисперсность частиц Cu.

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Sodesawa, T. Reduction behavior of Cu−SiO2 catalyst prepared by ion exchange for selective dehydrogenation to produce methyl formate from methanol. React Kinet Catal Lett 32, 51–56 (1986). https://doi.org/10.1007/BF02063449

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  • DOI: https://doi.org/10.1007/BF02063449

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