Abstract
For the hydrogenation of CO2 to CO, tungsten disulfide prepared by decomposing ammonium tetrathiotungstate, was found to exhibit high activity and good selectivity (>99.9%). Large surface area, viz., 64 m2g−1, is primarily responsible for the high activity, while the lack of activity in CO methanation for the good selectivity.
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References
For example, articles in Proc. Int. Symp. Chem. Fixation of CO2 1991, Nagoya (1991).
F. Solymosi, A. Erdőhelyi, M. Kocsis: J. Chem. Soc., Faraday Trans. 1,77, 1003 (1981).
F. Solymosi, A. Erdőhelyi, T. Bánsági: J Catal.,68, 371 (1981).
G. D. Weatherbee, C. H. Bartholomew: J. Catal.,68, 67 (1981).
M. Saito, R. B. Anderson: J. Catal.,67, 296 (1981).
H. Taoda, T. Osaki, K. Iseda, T. Horiuchi, H. Yamakita: Chem. Express,6, 1013 (1991).
T. Mori, H. Masuda, H. Imai, A. Miyamoto, S. Baba, Y. Murakami: J. Phys. Chem.,86, 2753 (1982).
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Osaki, T., Taoda, H., Horiuchi, T. et al. Tungsten disulfide prepared from ammonium tetrathiotungstate as a catalyst with high performance for the selective hydrogenation of CO2 to CO. React Kinet Catal Lett 51, 39–43 (1993). https://doi.org/10.1007/BF02062475
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DOI: https://doi.org/10.1007/BF02062475