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Inorganic particulates in removal of toxic heavy metal ions

IV. Efficient removal of zinc ions from aqueous solution by hydrous zirconium oxide

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Abstract

Adsorption behavior of zinc ions on hydrous zirconium oxide (HZO) in aqueous solution has been studied as a function of concentration (10−2–10−8M), temperature (303–333 K) and pH 3–8 of adsorptive solution applying radiotracer technique. The kinetics of adsorption follows first order rate law and agrees well with the classical Freundlich isotherm in the entire range of adsorptive concentration. The removal was found to be increasing with pH of the adsorptive solution while it was suppressed in the presence of acid concentrations. The overall process is found to be endothermic and irreversible in nature.

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References

  1. B. A. BROWN, A. A. BROWN, G. C. LALOR, Environ. Geochem. Health, 17 (1995) 545.

    Google Scholar 

  2. K. L. TOTAWAT, R. N. UPADHYAY, S. C. CHAUHAN, Ind. J. Environ. Health, 36 (1994) 237.

    Google Scholar 

  3. A. SHARMA, M. SHARMA, J. Environ. Biol., 15 (1994) 221.

    Google Scholar 

  4. V. N. IYER, R. SARIN, Asian Environ., 11 (1989) 39.

    Google Scholar 

  5. S. MUSIC, M. RISTIC, J. Radioanal. Nucl. Chem., 120 (1988) 289.

    Google Scholar 

  6. H. KAWANO, Y. NAKAI, T. MATSUDA, T. NAGAI, Talanta, 33 (1986) 191.

    Google Scholar 

  7. S. MUSTAFA, M. SAFDAR, G. NAWAB, Phys. Chem., 9 (1990) 79.

    Google Scholar 

  8. M. BRANDAO, B. SUELI, F. GALEMBECK, Colloids Surf., 48 (1990) 351.

    Google Scholar 

  9. S. MUSIC, M. RISTIC, J. Radioanal. Nucl. Chem., 162 (1992) 351.

    Google Scholar 

  10. S. M. HASANY, F. A. CHUGHTAI, A. GHAFFAR, Sep. Sci. Technol., 26 (1991) 1131.

    Google Scholar 

  11. G. MICERA, C. GESSA, P. MELIS, A. PREMOLI, R. DALLOCHIO, S. DEIANA, Colloids. Surf., 17 (1986) 386.

    Google Scholar 

  12. S. MUSTAFA, M. SAFDAR, S. Y. HUSSAIN, J. Surf. Sci. Technol., 5 (1989) 267.

    Google Scholar 

  13. H. TAMURA, M. NAGAYAMA, Prog. Batt. Sol. Cells, 5 (1984) 143.

    Google Scholar 

  14. M. RASHID, M. EJAZ, Appl. Radiation Isotopes, 37 (1986) 501.

    Google Scholar 

  15. S. P. MISHRA, V. K. SINGH, D. TIWARI, Appl. Radiation Isotopes, 47 (1995) 15.

    Google Scholar 

  16. H. S. MAHAL, B. VENKATRAMANI, K. S. VENKATESWARLU, J. Inorg. Nucl. Chem., 43 (1981) 3335.

    Google Scholar 

  17. J. A. GLADSDEN, Infrared Spectra of Minerals and Related Compounds, Butterworths, London, 1975.

    Google Scholar 

  18. S. P. MISHRA, N. SRINIVASU, D. TIWARY, Appl. Radiation Istopes, 43 (1992) 1253.

    Google Scholar 

  19. P. BENES, V. MAJER, Trace Chemistry of Aqueous Solution, Elsevier, Amsterdam, 1980.

    Google Scholar 

  20. F. HELFFERICH, Ion Exchange, McGraw Hill, New York, 1962.

    Google Scholar 

  21. M. OKAZAKI, K. TAKAMIDOH, I. YAMANE, Soil Sci. Plant Nutr., 32 (1986) 523.

    Google Scholar 

  22. G. A. PARKS, Chem. Rev., 65 (1965) 177.

    Google Scholar 

  23. B. VOLESKY, FEMS Microbiol. Rev., 14 (1994) 291.

    PubMed  Google Scholar 

  24. R. FUJIYOSHI, A. S. EUGENE, M. KATAYAMA, Appl. Radiation Isotopes, 43 (1992) 1223.

    Google Scholar 

  25. R. J. ZASOSKI, R. G. BURAU, Soil Sci. Soc. Am. J., 52 (1986) 81.

    Google Scholar 

  26. C. E. COWAN, J. M. ZACHARA, C. T. RESCH, Environ. Sci. Technol., 25 (1991) 437.

    Google Scholar 

  27. A. R. BOWERS, C. P. HUANG, J. Colloids Interface Sci., 105 (1985) 197.

    Google Scholar 

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Mishra, S.P., Singh, V.K. & Tiwari, D. Inorganic particulates in removal of toxic heavy metal ions. Journal of Radioanalytical and Nuclear Chemistry Articles 210, 207–217 (1996). https://doi.org/10.1007/BF02055419

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  • DOI: https://doi.org/10.1007/BF02055419

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