Abstract
Hydrogen isotope exchange reaction rate in tritium and methane mixed gas, as induced by tritium decay and beta radiation, has been experimentally measured. Initially T2 gas was filled to 40 kPa and 20 kPa of CH4 gas was added. The mixed gas spectrum was analyzed periodically by laser Raman spectrometry. The first order HT and H2 formation rates and T2 and CH4 decay rates by hydrogen isotope exchange reaction were observed between 2.9·10−3 h−1 and 4.8·10−3 h−1. Although the estimated hydrogen isotope exchange reaction rate was 1/20–1/10 slower than the rate of H2+T2 mixed gases, it was nearly equivalent to the ion formation rate by tritium beta radiation. This suggested that isotopic hydrogen radicals formed via ionization would disappear in the presence of methane.
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References
D. T. DAWSON, Methane impurity production in the fusion reactor, Report CFFTPG-85038, 1984.
R. YAMADA, J. Nucl. Mater., 145–147 (1987) 359.
Y. NARUSE, Y. MATSUDA, K. TANAKA, Fusion Eng. Design, 12 (1990) 293.
K. OKUNO, T. UDA, S. O'HIRA, Y. NARUSE, J. Nucl. Sci. Technol., 28 (1991) 509.
T. UDA, K. OKUNO, S. O'HIRA, Y. NARUSE, Fusion Technol., 19 (1991) 1651.
T. UDA, K. OKUNO, Y. NARUSE, Radiochim. Acta, to be published.
T. UDA, K. OKUNO, S. O'HIRA, Y. NARUSA, J. Nucl. Sci. Technol., 28 (1991) 618.
K. E. WILZBACH, J. Am. Chem. Soc., 79 (1957) 1013.
K. YANG, P. L. GANT, J. Chem. Phys., 31 (1959) 1589.
K. YANG, P. L. GANT, J. Phys. Chem., 66 (1962) 1619.
T. H. PRATT, R. WOLFGANG, J. Am. Chem. Soc., 83 (1961) 10.
L. M. RAFF, J. Chem. Phys., 60 (1974) 2220.
G. T. McCONVILLE, Synthesis and application of isotopically labeled compounds, Proc. 3rd Intern. Symp. Elsevier Sci. Publishers, Netherlands, 1989, p. 117.
M. GLUGLA, R. D. PENZHORN, J. L. ANDERSON, J. R. BARTLIT, Fusion Technol., 14 (1988) 683.
LIND, C. J. HOCHANADEL, J. A. GHORMLEY, Radiation Chemistry of Gases, Reinhold Publishing Co., New York, 1961.
G. HUGHES, Radiation Chemistry, Clarendon Press, Oxford, 1973.
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Uda, T., Okuno, K. & Naruse, Y. Hydrogen isotope exchange reaction rate in tritium and methane mixed gas. Journal of Radioanalytical and Nuclear Chemistry, Articles 159, 145–154 (1992). https://doi.org/10.1007/BF02041027
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DOI: https://doi.org/10.1007/BF02041027