Abstract
Sequential extraction techniques have been utilized in order to investigate the degree of binding or association of natural iodine127I and the radioactive iodine isotope129I with soil components. The results indicate that only a small fraction of natural iodine (2.5–4%) but a large fraction of the recently added radioactive129I (38–49%) is water-soluble. The other forms of iodine which were determined for both iodine isotopes were exchangeable iodine, iodine bound to metal-oxides and iodine bound to organic matter.
Similar content being viewed by others
References
E. ROBENS, J. HAUSCHILD, D. C. AUMANN, J. Environ. Radioactivity, 7 (1988) 265.
E. ROBENS, J. HAUSCHILD, D. C. AUMANN, J. Environ. Radioactivity, 8 (1988) 37.
J. HAUSCHILD, D. C. AUMANN, J. Environ. Radioactivity, 9 (1989) 145.
W. I. DEITERMANN, J. HAUSCHILD, E. ROBENS-PALAVINSKAS, D. C. AUMANN, J. Environ. Radioactivity, 10 (1989) 79.
K. SCHMITZ, D. C. AUMANN, J. Environ. Radioactivity, 24 (1994) 91.
R. FUGE, C. C. JOHNSON, Environ. Geochem. Health, 8 (1986) 31.
M. E. RAJA, K. L. BABCOCK, Soil Sci., 91 (1961) 1.
G. W. REED, R. O. ALLEN, Geochim. Cosmochim. Acta, 30 (1966) 779.
A. SAAS, Radioprotection, 11 (1966) 205.
D. C. WHITEHEAD, J. Soil Sci., 29 (1978) 88.
D. C. WHITEHEAD, J. Soil Sci., 24 (1973) 260.
G. G. GOLES, E. ANDERS, Geochim. Cosmochim. Acta, 26 (1962) 723.
S. MUSIČ, J. SIPALO-ZULJEVIČ, R. H. H. WOLF, Isotopenpraxis, 15 (1979) 93.
K. TENSHO, K. L. YEH, Soil Sci. Plant Nutr., 16 (1970) 30.
D. C. WHITEHEAD, J. Soil Sci., 25 (1974) 461.
D. C. WHITEHEAD, J. Sci. Food Agric., 24 (1973) 43.
B. T. WILKINS, Investigations of Iodine-129 in the environment: Results and implications. National Radiological Protection Board Report NRPB-R225, United Kingdom, 1989.
P. W. ARNOLD, J. Soil Sci., 28 (1977) 393.
H. BOHN, B. McNEAL, G. O'CONNOR, Soil Chemistry, 2nd ed., John Wiley, New York, 1985.
G. A. FLEMING, Essential Micronutrients II: Iodine and Selenium. In: Applied Soil Trace Elements, B. E. DAVIES (Ed.), John Wiley, New York, 1980.
F. SCHEFFER, P. SCHACHTSCHABEL, Lehrbuch der Bodenkunde, Verlag Ferdinand Enke, Stuttgart, 1979.
R. KRETZSCHMAR, Kulturchemisch-Bodenkundliches Praktikum. Ausgewählte Laboratoriumsmethoden. Christian-Albrechts-Universität Kiel, Institut für Wasserwirtschaft und Meliorationswesen, 1984.
A. L. PAGE, R. H. MILLER, D. R. KEENEY (Eds) Methods in Soil Analysis, Part 2: Chemical and Microbiological Properties, American Society of Agronomy, Inc. Soil Science Society of America, Inc. (Publ.), Madison, Wisconsin, USA, 1982.
H. BILTZ, Chem. Ber., 29 (1896) 2080.
E. MÜLLER, O. BAYER, H. MEERWEIN, K. ZIEGELER (Eds), Methoden der organischen Chemie, Band 1, Georg-Thieme-Verlag, Stuttgart, 1953.
International Union of Radioecologists, Recommendations for the determination of transfer factors, in: 4th Report of the Workgroup on Soil-to-Plant Transfer Factors, M. J. FRISSEL (Ed.), RIVM, Bilthoven, The Netherlands, 1985.
D. C. AUMANN, H. FALESCHINI, L. FRIEDMANN, Radiochim. Acta, 28 (1981) 209.
D. C. AUMANN, F. BUHEITEL, J. HAUSCHILD, E. ROBENS, H. WERSHOFEN, J. Radioanal. Nucl. Chem., 109 (1987) 261.
B. L. COHEN, Health Phys., 45 (1985) 279.
H. BEHRENS, Speciation of Radioiodine in aquatic and terrestrial systems under the influence of biogeochemical processes, in: R. A. BULMAN, J.R. COOPER, (Eds), Speciation of Fission and Activation Products in the Environment, Elsevier Applied Science Publ., London, New York, 1985.
J. V. CHRISTIANSEN, L. CARLSEN, Radiochim. Acta, 52/53 (1991) 327.
L. A. MAGOMEDOVA, N. G. ZYRIN, A. B. SALMANOV, Agrokhimiya, 1 (1970) 117.
A. SAAS, Géochimie de l'iode dans les principaux types de sols français, Extrait du procès verbal de la Séance du 21.1. 1981, p. 161.
A. TESSIER, P. G. C. CAMPBELL, M. BISSON, Anal. Chem., 51 (1979) 844.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Schmitz, K., Aumann, D.C. A study on the association of two iodine isotopes, of natural127I and of the fission product129I, with soil components using a sequential extraction procedure. Journal of Radioanalytical and Nuclear Chemistry, Articles 198, 229–236 (1995). https://doi.org/10.1007/BF02038260
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02038260