Skip to main content
SpringerLink
Log in

Some parameters affecting column distribution ratios of Am(III) and Eu(III) and column resolution of TBP impregnated macroporous XAD-4 polymers

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The separation of the trivalent metal ions Am(III) and Eu(III) by extraction chromatography employing TBP impregnated macroporous XAD-4 resin as the stationary phase was examined; some parameters affecting the distribution ratio (Kd) and the column resolution (Rs) of Am(III) and Eu(III) were investigated. These parameters are the effect of TBP loading, aqueous nitrate concentrations, and flow rate. Both Kd andRs increase with the TBP loading.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. E. LOUIS, G. DUYCKAERTS, J. Radioanal. Nucl. Chem. 81 (1984) 305.

    Google Scholar 

  2. E. P. HORWITZ, C. A. A. BLOOMQUIST, D. J. HENDERSON, D. E. NELSON, J. Inorg. Nucl. Chem., 31 (1969) 3255.

    Article  Google Scholar 

  3. E. P. HORWITZ, C. A. A. BLOOMQUIST, J. Inorg. Nucl. Chem., 35 (1973) 271.

    Article  Google Scholar 

  4. G. F. BEST, H. HESFORD, H. A. C. McKAY, J. Inorg. Nucl. Chem., 12 (1959) 136.

    Article  Google Scholar 

  5. A. WARSHASWKY, A. PATCHORNIK, Israel J. Chem., 17 (1978) 307.

    Google Scholar 

  6. D. A. ORTH, J. M. McKIBBEN, W. E. PROUT, W. C. SCOTTEN, Proc. Intern. Solvent Extraction Conf. (ISEC), The Hague, 1971, Vol. 1, p. 534.

  7. R. KROEBEL, A. MEYER, Proc. Intern Solvent Extraction Conf. (ISEC), Toronto, Canada, 1974, Vol. 3, p. 2095.

    Google Scholar 

  8. H. ESCHRICH, W. OCHSENFELD, Separ. Sci. Techn., 15 (1980), 697.

    Google Scholar 

  9. ROHM and HAAS Co., Preliminary Technical Notes, Amberlite XAD-4 (1971), Philadelphia, Pennsylvania 19105, USA.

Download references

Author information

Authors and Affiliations

  1. Nuclear Research Center, Tawaitha, Baghdad, (Iraq)

    R. E. Louis

  2. Laboratory of Analytical Chemistry and Radiochemistry, University of Liège, B-4000, Sart Tilman-Liège, (Belgium)

    G. Duyckaerts

Authors
  1. R. E. Louis
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Duyckaerts
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Louis, R.E., Duyckaerts, G. Some parameters affecting column distribution ratios of Am(III) and Eu(III) and column resolution of TBP impregnated macroporous XAD-4 polymers. Journal of Radioanalytical and Nuclear Chemistry, Articles 90, 105–112 (1985). https://doi.org/10.1007/BF02037325

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02037325

Keywords

Search

Navigation