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Adsorption behaviour of microamounts of cesium on manganese dioxide

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Abstract

The adsorption of cesium on manganese dioxide from aqueous solutions has been studied in relation to pertinent variables such as shaking time, pH, composition of aqueous solutions, mass of adsorbent (10 mg–1 g) and concentration of adsorbate (10−6–5·10−3 M), using a radiotracer technique. The influence of various anions and cations on cesium adsorption was examined. The distribution coefficient of a variety of other elements was determined under similar conditions. The adsorption of cesium obeys a Freundlich-type isotherm over the entire concentration range investigated, whereas the Langmuir-type isotherm is followed only at moderate concentrations.

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References

  1. R. W. DALTON, J. L. McCLANAHAN, R. W. MAATMAN, J. Colloid Sci., 17 (1962) 207.

    Article  Google Scholar 

  2. J. BELLONI-COFLER, D. PAVOLOV, J. Chim. Phys., 62 (1965) 458.

    Google Scholar 

  3. H. T. TIEN, J. Phys. Chem., 69 (1965) 350.

    Google Scholar 

  4. J. HORSKI, INR Rept. No. 636, Warsaw, Poland, May, 1965.

  5. C. H. HEITNER-WIRGUIN, A. ALBU-YARON, J. Inorg. Nucl. Chem., 28 (1966) 2379.

    Article  Google Scholar 

  6. B. E. CHIDLEY, F. L. PARKER, E. A. TALBOT, Rept. No. AERE-R 5220, Harwell, U.K., October, 1966.

  7. L. H. BAETSLE, D. HUYS, J. Inorg. Nucl. Chem., 30 (1968) 639.

    Article  Google Scholar 

  8. Th. F. TADROS, J. LYKLEMA, J. Electroanal. Chem., Interfacial Electrochem., 17 (1968) 267.

    Google Scholar 

  9. H. W. VON LEVI, E. SCHIEWER, Radiochim. Acta, 9 (1968) 160.

    Google Scholar 

  10. M. ABE, Bull. Chem. Soc. Japan, 42 (1969) 2683.

    Google Scholar 

  11. R. CALETKA, T. D. ZAITSEVA, Radiokhimiya, 11 (1969) 510.

    Google Scholar 

  12. L. H. ALLEN, E. MATIJEVIC, J. Colloid Interface Sci., 31 (1969) 287.

    Article  Google Scholar 

  13. J. D. DONALDSON, M. J. FULLER, J. Inorg. Nucl. Chem., 32 (1970) 1703.

    Article  Google Scholar 

  14. I. N. BOURRELLY, N. DECHAMPS, J. Radioanal. Chem., 8 (1971) 303.

    Google Scholar 

  15. M. A. MALATI, R. J. MAZZA, A. J. SHERREN, D. R. TOMPKINS, Powder Technol., 9 (1974) 107.

    Article  Google Scholar 

  16. Yu. G. FROLOV, S. K. MITONIC, V. L. RAZIN, Kolloidn. Zh., 41 (1974) 516.

    Google Scholar 

  17. V. I. PLOTNIKOV, T. I. TAURBAEVA, Radiokhimiya, 17 (1975) 338.

    Google Scholar 

  18. T. SZALAY, L. BARTHA, T. NÉMETH, Magy. Kém. Foly., 82 (1976) 135.

    Google Scholar 

  19. V. I. PLOTNIKOV, T. I. TAURBAEVA, Radiokhimiya, 19 (1977) 20.

    Google Scholar 

  20. B. VENKATARANMANI, K. S. VENKATAWARLU, J. SHANKER, Proc. Indian Acad. Sci. Sec. A, 87A (1978) 409.

    Google Scholar 

  21. G. A. KOKAREV, M. Ya. FIOSHIN, V. E. KAZARINOV, N. T. GOROKHOVA, V. A. KOLESNIKOV, Dvoinoi Soli Adsorbtsiya Tverd. Electrodakh, 5 (1978) 93.

    Google Scholar 

  22. N. Z. MISAK, E. M. MIKHAIL, J. Appl. Chem. Biotechnol., 28 (1978) 499.

    Google Scholar 

  23. M. ABE, J. Inorg. Nucl. Chem., 41 (1979) 85.

    Article  Google Scholar 

  24. C. BIGLIOCCA, F. GIRARDI, J. PAULY, E. SABBIONI, S. MELONI, A. PROVASOLI, Anal. Chem., 39 (1967) 1634.

    Article  Google Scholar 

  25. S. MELONI, A. BRANDONE, Radiochim. Acta, 10 (1968) 97.

    Google Scholar 

  26. A. I. MUN, A. S. SABAEV, R. S. DARER, Izv. Akad. Nauk. Kaz. SSR Ser. Khim., 24 (1974) 16.

    Google Scholar 

  27. A. I. MUN, R. E. ZHAIMINA, R. S. DARER, A. S. SABAEV, U. T. ISEZHULVA, Tr. Inst. Khim. Nauk., Akad. Nauk. Kaz SSR., 40 (1975) 82.

    Google Scholar 

  28. A. S. SAKAEV, Vestn. Akad. Nauk. Kaz SSR., 64 (1975).

  29. R. E. ZHAIMINA, A. I. MUN, A. S. SABAEV, Izv. Akad. Nauk. Kaz. SSR., Ser. Khim., 25 (1975) 12.

    Google Scholar 

  30. O. V. SINGH, S. N. TANDON, Intern. J. Appl. Radiation Isotopes, 28 (1977) 701.

    Article  Google Scholar 

  31. S. M. HASANY, M. A. QURESHI, Intern. J. Appl. Radiation Isotopes, 32 (1981) 747.

    Article  Google Scholar 

  32. S. M. HASANY, M. H. CHAUDHARY, Intern. J. Appl. Radiation Isotopes, 32 (1981) 899.

    Article  Google Scholar 

  33. F. KEPAK, M. NUDERVA, J. KANKA, J. Radioanal. Chem., 14 (1973) 325.

    Google Scholar 

  34. J. Van R. SMIT, AERE-R 3884 Report U.K. At. Energy Estb., Harwell, U.K., November, 1961.

  35. J. Van R. SMIT, J. J. JACOBS, Ind. Eng. Chem. Process Des. Dev., 5 (1966) 117.

    Article  Google Scholar 

  36. H. T. MATSUDA, Ph.D. Thesis, University of Sao Paulo, 1977.

  37. M. SUSS, G. PFREPPER, Radiochim. Acta, 29 (1981) 33.

    Google Scholar 

  38. C. R. WEAST, Handbook of Chemistry and Physics, 55th Ed., F-198, CRC Press, Cleveland, Ohio, 1974.

    Google Scholar 

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Authors and Affiliations

  1. Nuclear Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Rawalpindi, (Pakistan)

    S. M. Hasany & M. H. Chaudhary

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  1. S. M. Hasany
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  2. M. H. Chaudhary
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Hasany, S.M., Chaudhary, M.H. Adsorption behaviour of microamounts of cesium on manganese dioxide. Journal of Radioanalytical and Nuclear Chemistry, Articles 84, 247–256 (1984). https://doi.org/10.1007/BF02036963

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  • DOI: https://doi.org/10.1007/BF02036963

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