Abstract
The determination of carbon, hydrogen, nitrogen, fluorine, chlorine and sulphur contents for characterization of plutonium complexes with organic ligands have been standardized and glove box adopted. Various plutonium(IV) mono- and di-carboxylates, plutonium(IV) chelates with pyrazolones, UO ++2 and PuO ++2 complexes having pyrazolones as chelating agent and sulfoxides, amides and phosphine oxide ligands as oxodonors; uranium carbides and uranium nitrides and several potential organic extractants for actinides were analyzed satisfactorily. All these methods set up in double module glove box train are extremely useful for a low budget radioactive laboratory engaged in research in solid actinide complexes.
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Ruikar, P.B., Nagar, M.S. Utility of conventional analytical methods in characterization of organo-plutonium complexes. Journal of Radioanalytical and Nuclear Chemistry Articles 191, 15–24 (1995). https://doi.org/10.1007/BF02035980
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DOI: https://doi.org/10.1007/BF02035980