Abstract
A radiochemical method has been developed for the determination of99Tc in low-level radioactive, waste from nuclear facilities, using99mTc as an internal tracer. Radioactive contaminants were removed by carrier hydroxide precipitation and chelating extraction with NaDDC/CHCl3 system at pH 4. The final technetium was chelated with NaDDC in 3N HCl solution and extracted selectively into chloroform. The average of radiochemical recovery for various types of LLW sample is about 90%. The decontamination factors for most radioactive nuclides are higher than 105. The detection limit for99Tc in a sample of about 10 g is 0.17 pCi/g (6.5 Bq·kg−1) for a 100-minute count.
Similar content being viewed by others
References
IOCFR Part 61, Licensing Requirements for Land Disposal of Radioactive Waste, 1982.
N. Y. CHU, J. FELDSTEIN, Talanta, 31 (1984) 809.
E. HOLM, J. RIOSECO, S. BALLESTRA, A. WALTON, J. Radioanal. Nucl. Chem., 123 (1988) 167.
J. P. RILEY, S. A. SIDDIOUI, Anal. Chim. Acta, 139 (1982) 167.
M. KOIDE, E. D. GOLDBERG, J. Environ. Radioactivity, 2 (1985) 261.
S. FOTI, E. DELUCCHI, V. AKAMIAN, Anal. Chim. Acta, 60 (1972) 269.
M. OTSUJI, R. SEKI, N. IKEDA, Radioisotopes, 36 (1987) 36.
P. ROBB, P. WARWICK, D. J. MALCOLME-LAWES, J. Radioanal. Nucl. Chem., 89 (1985) 323.
S. HIRANO, M. MATSUBA, H. KAMADA, Radioisotopes, 38 (1989) 186.
N. W. GOLCHERT, J. SEDLET, Anal. Chem., 41 (1969) 669.
M. GARCÍA-LEÒN, J. Radioanal. Nucl. Chem., 138 (1990) 171.
M. GARCÍA-LEÒN, C. I. SANCHEZ-ANGULO, J. Radioanal. Nucl. Chem., 115 (1987) 377.
M. GARCÍA-LEÒN, C. PIAZZA, G. MADURGA, Int. J. Appl. Radiation Isotopes, 35 (1984) 961.
M. GARCÍA-LEÒN, G. MADURGA, Int. J. Appl. Radiation Isotopes, 36 (1985) 129.
G. BIDOGLIO, A. CHATT, A. DE PLANO, E. ZORN, J. Radioanal. Chem., 79 (1983) 153.
K. V. KOTEGOV, O. N. PAVIOV, V. P. SHVEDOV, Adv. Inorg. Chem., 7 (1968) 1.
J. E. MARTIN, J. M. HYLKO, J. Appl. Radiation Isotopes, 38 (1987) 447.
R. J. SILVA, R. EVANS, J. H. GEGO, R. W. BUDDEMEIER, J. Radioanal. Nucl. Chem., 124 (1988) 397.
G. E. BOYD, O. V. LARSON, J. Phys. Chem., 64 (1960) 988.
S. HIRANO et al. Radioisotopes, 38 (1989) 186.
J. M. LO, J. C. WEI, S. J. YEH, Anal. Chim. Acta, 97 (1978) 311.
J. D. KINRADE, J. C. VAN LOON, Anal. Chem., 46 (1974) 1894.
D. CHAKRABORTI et al., Anal. Chim. Acta, 196 (1987) 23.
J. M. LO, J. C. Yu., F. I. HUTCHISON, C. M. WAI, Anal Chem., 54 (1982) 2536.
J. M. LO, J. C. WEI, M. H. YANG, S. J. YEH, J. Radioanal. Chem., 72 (1982) 571.
Y. KUSAKA, H. TSUJI, Y. TAMARI, T. SAGAWA, S. OHMORI, S. IMAI, T. OZAKI, J. Radioanal. Chem., 37 (1977) 917.
L. G. DANIELSSON, B. MAGNUSSON, S. WESTERLUND, Anal. Chim. Acta, 98 (1978) 47.
B. MAGNUSSON, S. WESTERLUND, Anal. Chim. Acta, 131 (1981) 63.
H. VOLCHOK, G. DE PLANQUE (Eds), EML Procedures Manual, U.S. Dept. Energy Repot., HASL-300, 25th ED., New York, 1982.
C. R. WALKER, B. W. SHORT, H. S. SPRING, The Determination of99Tc by Liquid Scintillation Counting in Radioelement Analysis' Progress and Problems, W. S. LYON, (Ed.) Ann Arbor, 1980.
B. SJÖSTRAND, Anal. Chem., 36 (1964) 815.
Mercury Analysis Working Party of BITC, Anal. Chim. Acta, 84 (1976) 231.
J. DE LIVERANT, W. WOLF, Int. J. Appl. Radiation Isotopes, 33 (1982) 857.
A. MIZUIKE, Enrichment Techniques for Inorganic Trace Analysis. Springer-Verlag, Berlin-Heidelberg-New York, 1983.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chiu, J.H., Chu, T.C. & Weng, P.S. Radiochenical determination of technetium-99 in LLW by chelation with sodium diethyl dithiocarbamate (NaDDC) and extraction with chloroform. Journal of Radioanalytical and Nuclear Chemistry, Articles 150, 493–507 (1991). https://doi.org/10.1007/BF02035336
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02035336