Abstract
Thermochemical and thermodynamical properties of HTSC phases are reviewed for the Y-Ba-Cu-O system and also presented for the newly calculated Bi-Sr-Cu-O system stressing out stoichiometric and phenomenological viewpoints. Simulated data are listed for (H o298 -H oo , phase transformation temperatures, standard entropies, standard enthalpies of formation, heat capacities in crystalline phase, etc. Pseudobinary phase diagrams are treated showing the effect of oxygen partial pressure particularly illustrated on the (Sr, Bi, Ba)-Cu-O system.
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The work was carried out under the project No. A 2010532 supported by the Grant Agency of Academy of Sciences of the Czech Republic and the grant No. 104/97/0589 financed by the Grant Agency of the Czech Republic.
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Šesták, J., Sedmidubsky, D. & Moiseev, G. Some thermodynamic aspects of highT c superconductors. Journal of Thermal Analysis 48, 1105–1122 (1997). https://doi.org/10.1007/BF01979157
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DOI: https://doi.org/10.1007/BF01979157