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Compensation effect in solid-state reactions. Thermolysis of one substance under differing experimental conditions

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Abstract

The compensation effect (lgZ=aE+wb) appearing at the thermolysis of one substance under different experimental conditions is discussed. The compensation effect of one and the same substance has no other physical meaning except the simple confirmation of the analytical relationship between lgZ andE that follows from the Arrhenius equation, and of the impossibility to determineZ from any independent experiment. Values of the coefficienta can not be the measure of the ruptured bond strength.

Резюме

Рассмотрен компенса ционный эффект (lgZ=аЕ+b), наблюдаемый експери ментально при изменении услови й термолиза одного вещества. Компенсаци онный эффект для одного и то го же вещества не имее т другого физического смысла, к роме констатации аналитической завис имости между lgZ иE (вытекающей из уравне ния Аррениуса) и невозможности опре деления величиныZ из независимого экспер имента. Величина коеффициентаa не мож ет служить мерой силы разрываемой связи.

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Authors and Affiliations

  1. Sibirian Department of the Academy of Sciences of the U.S.S.R., Institute of Inorganic Chemistry, Novosibirsk

    A. V. Nikolaev & V. A. Logvinenko

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  1. A. V. Nikolaev
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  2. V. A. Logvinenko
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Nikolaev, A.V., Logvinenko, V.A. Compensation effect in solid-state reactions. Thermolysis of one substance under differing experimental conditions. Journal of Thermal Analysis 10, 363–368 (1976). https://doi.org/10.1007/BF01909887

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  • DOI: https://doi.org/10.1007/BF01909887

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