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Theory of monomer-dimer systems

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Abstract

We investigate the general monomer-dimer partition function,P(x), which is a polynomial in the monomer activity,x, with coefficients depending on the dimer activities. Our main result is thatP(x) has its zeros on the imaginary axis when the dimer activities are nonnegative. Therefore, no monomer-dimer system can have a phase transition as a function of monomer density except, possibly, when the monomer density is minimal (i.e.x=0). Elaborating on this theme we prove the existence and analyticity of correlation functions (away fromx=0) in the thermodynamic limit. Among other things we obtain bounds on the compressibility and derive a new variable in which to make an expansion of the free energy that converges down to the minimal monomer density. We also relate the monomer-dimer problem to the Heisenberg and Ising models of a magnet and derive Christoffell-Darboux formulas for the monomer-dimer and Ising model partition functions. This casts the Ising model in a new light and provides an alternative proof of the Lee-Yang circle theorem. We also derive joint complex analyticity domains in the monomer and dimer activities. Our considerations are independent of geometry and hence are valid for any dimensionality.

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References

  1. Roberts, J.K.: Proc. Roy. Soc. (London) A152, 469 (1935).

    Google Scholar 

  2. —— Proc. Roy. Soc. (London) A161, 141 (1937).

    Google Scholar 

  3. —— Proc. Cambridge Phil. Soc.34, 399 (1938).

    Google Scholar 

  4. —— Miller, A. R.: Proc. Cambridge Phil. Soc.35, 293 (1939).

    Google Scholar 

  5. Readhead, P. A.: Trans. Faraday Soc.57, 641 (1961).

    Google Scholar 

  6. Rossington, D. R., Bost, R.: Surface Sci.3, 202 (1965).

    Google Scholar 

  7. Lichtman, D., McQuistan, R. B.: J. Math. Phys.8, 2441 (1967).

    Google Scholar 

  8. McQuistan, R. B., Lichtman, D.: J. Math. Phys.9, 1660 (1968).

    Google Scholar 

  9. —— J. Math. Phys.10, 2205 (1969).

    Google Scholar 

  10. —— Lichtman, S. J.: J. Math. Phys.11, 3095 (1970).

    Google Scholar 

  11. Fowler, R. H., Rushbrooke, G. S.: Trans. Faraday Soc.33, 1272 (1937).

    Google Scholar 

  12. Guggenheim, A.: Trans. Faraday Soc.33, 151 (1937).

    Google Scholar 

  13. Chang, T. S.: Proc. Roy. Soc. (London) A169, 512 (1939).

    Google Scholar 

  14. —— Proc. Cambridge Phil. Soc.35, 265 (1939).

    Google Scholar 

  15. Miller, A. R.: Proc. Cambridge Phil. Soc.38, 109 (1942).

    Google Scholar 

  16. Orr, W. J. C.: Trans. Faraday Soc.40, 306 (1944).

    Google Scholar 

  17. McGlashan, M. L.: Trans. Faraday Soc.47, 1042 (1951).

    Google Scholar 

  18. Miller, A. R.: Proc. Cambridge Phil. Soc.39, 54 (1943).

    Google Scholar 

  19. —— Proc. Cambridge Phil. Soc.39, 131 (1943).

    Google Scholar 

  20. Orr, W. J. C.: Trans. Faraday Soc.40, 320 (1944).

    Google Scholar 

  21. Guggenheim, E. A.: Proc. Roy. Soc. (London) A183, 203 (1944).

    Google Scholar 

  22. —— Proc. Roy. Soc. (London) A183, 213 (1944).

    Google Scholar 

  23. We shall not attempt to give a complete bibliography of the Flory-Huggins theory; the reader is referred to standard textbooks. The earliest references seem to be P. J. Flory: J. Chem. Phys.10, 51 (1942) and Huggins: Ann. N. Y. Acad. Sci.43, 9 (1942).

    Google Scholar 

  24. Guggenheim, E. A.: Mixtures, Chapter X. Oxford: Claredon Press 1952.

    Google Scholar 

  25. Rushbrooke, G. S., Scoins, H. I., Wakefield, A. J.: Discussions Farad. Soc.15, 57 (1953).

    Google Scholar 

  26. Travena, D. H.: Proc. Phys. Soc.84, 969 (1964).

    Google Scholar 

  27. Nagle, J. F.: Phys. Rev.152, 190 (1966).

    Google Scholar 

  28. Gaunt, D. S.: Phys. Rev.179, 174 (1969).

    Google Scholar 

  29. Bellemans, A., Fuks, S.: Physica50, 348 (1970).

    Google Scholar 

  30. Runnels, L. K.: J. Math. Phys.11, 842 (1970).

    Google Scholar 

  31. Baxter, R. J.: J. Math. Phys.9, 650 (1968).

    Google Scholar 

  32. Craen, J. van, Bellemans, A.: Bull. Acad. Pol. Sci.19, 45 (1971).

    Google Scholar 

  33. Hammersley, J. M.: In: Proceedings of the 2nd Annual Conference on Computational Physics, pp. 1–8 (Institute of Physics and Physical Society, London (1970)).

    Google Scholar 

  34. Baxendale, J. H., Enüstün, B. V., Stern, J.: Phil. Trans. Roy. Soc. (London) A243, 169 (1951).

    Google Scholar 

  35. Everett, D. H., Penney, M. F.: Proc. Roy. Soc. (London) A212, 164 (1952).

    Google Scholar 

  36. Tompa, H.: J. Chem. Phys.16, 292 (1948).

    Google Scholar 

  37. Brøndsted, J. N., Koefoed, J.: Kgl. Danske Videnskab. Selskob. Mat-Fys. Medd.22, No. 17 (1946).

  38. Tompa, H.: Trans. Faraday Soc.45, 101 (1949).

    Google Scholar 

  39. Pizzini, S., Morlotti, R., Wagner, V.: J. Electrochem. Soc.116, 915 (1969).

    Google Scholar 

  40. Cohen, E. G. D., De Boer, J., Salsburg, Z. W.: Physica21, 137 (1955).

    Google Scholar 

  41. Conway, B. E., Verall, R. E.: J. Phys. Chem.70, 1473 (1966).

    Google Scholar 

  42. Fisher, M. E., Temperley, H. N. V.: Rev. Mod. Phys.32, 1029 (1960).

    Google Scholar 

  43. Katsura, S., Inawashiro, S.: Rev. Mod. Phys.32, 1031 (1960).

    Google Scholar 

  44. Kasteleyn, P. W.: Physica, Grav.27, 1209 (1961).

    Google Scholar 

  45. Temperley, H. N. V., Fisher, M. E.: Phil. Mag. Serie 86, 1061 (1961).

    Google Scholar 

  46. Fisher, M. E.: Phys. Rev.124, 1664 (1961).

    Google Scholar 

  47. Kasteleyn, P. W.: J. Math. Phys.4, 287 (1963).

    Google Scholar 

  48. Montroll, E. W.: In: Applied combinatorial mathematics (Ed. F. Beckenbach). New York: J. Wiley & Sons, 1964.

    Google Scholar 

  49. Lieb, E. H.: J. Math. Phys.8, 2339 (1967).

    Google Scholar 

  50. Gibberd, R. W.: Can. J. Phys.46, 1681 (1968).

    Google Scholar 

  51. Wu, T. T.: J. Math. Phys.3, 1265 (1962).

    Google Scholar 

  52. Ferdinand, A. E.: J. Math. Phys.8, 2332 (1967).

    Google Scholar 

  53. Hammersley, J. M., Feuerverger, A., Izenman, A., Mahani, S.: J. Math. Phys.10, 443 (1969).

    Google Scholar 

  54. Fisher, M. E., Stephenson, J.: Phys. Rev.132, 1411 (1963).

    Google Scholar 

  55. Hartwig, R. E.: J. Math. Phys.7, 286 (1966).

    Google Scholar 

  56. Bondy, J. A., Welsh, D. J. A.: Proc. Cambridge Phil. Soc. Math. Phys. Sci.62, 503 (1966).

    Google Scholar 

  57. Hammersley, J. M.: Proc. Cambridge Phil. Soc. Math. Phys. Sci.64, 455 (1968).

    Google Scholar 

  58. —— Menon, V. V.: J. Inst. Math. Appl.6, 341 (1970).

    Google Scholar 

  59. —— In: Research papers in statistics. Festschrift für J. Neyman, p. 125 (Editor, F. N. David). New York: John Wiley & Sons 1966.

    Google Scholar 

  60. Heilmann, O. J.: Existence of phase transitions in certain lattice gases with repulsive potentials (to be published).

  61. —— Lieb, E. H.: Phys. Rev. Letters24, 1412 (1970).

    Google Scholar 

  62. Kunz, H.: Phys. Letters32, 311 (1970).

    Google Scholar 

  63. Gruber, C., Kunz, H.: Commun. math. Phys.22, 133 (1971).

    Google Scholar 

  64. Dobrushin, R. L.: Funct. Anal. Appl.2, No. 4, 44 (1968), (English translation2, 302 (1968)).

    Google Scholar 

  65. Essam, J. W., Fisher, M. E.: Rev. Mod. Phys.42, 271 (1970).

    Google Scholar 

  66. Szegö, G.: Orthogonal polynomials (American Mathematical Society, Colloquium Publications Vol. XXIII, Providence 1939).

  67. Ruelle, D.: Statistical mechanics. New York: W. A. Benjamin 1969.

    Google Scholar 

  68. Fisher, M. E.: J. Math. Phys.7, 1776 (1966).

    Google Scholar 

  69. Lee, T. D., Yang, C. N.: Phys. Rev.87, 410 (1952).

    Google Scholar 

  70. Asano, T.: J. Phys. Soc. Japan29, 350 (1970); Phys. Rev. Letters24, 1409 (1970).

    Google Scholar 

  71. Suzuki, M., Fisher, M. E.: J. Math. Phys.12, 235 (1971).

    Google Scholar 

  72. Ginibre, J.: Phys. Letters24, 223 (1967).

    Google Scholar 

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Work supported by National Science Foundation Grant GP-26526.

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Heilmann, O.J., Lieb, E.H. Theory of monomer-dimer systems. Commun.Math. Phys. 25, 190–232 (1972). https://doi.org/10.1007/BF01877590

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