Skip to main content
Log in

A model of Martian surface chemistry

  • The Biological Experiments
  • Published:
Journal of Molecular Evolution Aims and scope Submit manuscript

Summary

Alkaline earth and alkali metal superoxides and peroxides,γ-Fe2O3 and carbon suboxide polymer are proposed to be constituents of the Martian surface material. These reactive substances explain the water modified reactions and thermal behaviors of the Martian samples demonstrated by all of the Viking Biology Experiments. It is also proposed that the syntheses of these substances result mainly from electrical discharges between wind-mobilized particles at Martian pressures; plasmas are initiated and maintained by these discharges. Active species in the plasma either combine to form or react with inorganic surfaces to create the reactive constitutents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Baird, A.K., Toulmin, III, P., Clark, B.C., Rose, Jr., H.J., Keil, K., Christian, R.P., Gooding, J.L. (1976). Science194, 1288–1293

    Google Scholar 

  • Ballou, E.V., Wood, P.C., Wydeven, T., Lehwalt, M.E., Mack, R.E. (1978). Nature271, 644–645

    Google Scholar 

  • Biemann, K. (1978). Presented at COSPAR Meeting, May 29–June 10, 1978. Innsbruck, Austria, Oxford: Pergamon

    Google Scholar 

  • Blake, A.R., Hyde, A.F. (1964). Trans. Faraday Soc.60, 1775–1782

    Google Scholar 

  • Clark, B.C., Baird, A.K., Rose, Jr., H.J., Toulmin, III, P., Keil, K., Castro, A.J., Kelliher, W.C., Rowe, C.D., Evans, P.H. (1976). Science194, 1283–1288

    Google Scholar 

  • Clark, W.M. (1927). The Determination of Hydrogen Ions, Baltimore: Williams and Wilkens

    Google Scholar 

  • Cohen, S.H., Margrave, J.L. (1957). Anal. Chem.29, 1462–1463

    Google Scholar 

  • Cotton, F.A., Wilkinson, G. (1966). Advanced Inorganic Chemistry, p. 375. New York: Interscience

    Google Scholar 

  • Diels, O., Wolf, B. (1906). Ber.39, 689–697

    Google Scholar 

  • Eden, H.F., Vonnegut, B. (1973). Science180, 962–963

    Google Scholar 

  • Farmer, C. B. (1976). Icarus28, 279–289

    Google Scholar 

  • Faucitano, A., Maxia, V. (1963). Ric. Sci., Parte 2: Sez A3, 131–140

    Google Scholar 

  • Hargraves, R.B., Collinson, D.W., Arvidson, R.E., Spitzer, C.R. (1976). Science194, 1303–1309

    Google Scholar 

  • Harteck, P., Dondes, S. (1955). J. Chem. Phys.23, 902–908

    Google Scholar 

  • Hochanadel, C.J., Ghormley, J.A., Ogren, P.J. (1972). J. Chem. Phys.56, 4426–4432

    Google Scholar 

  • Hodgman, C.D., ed. (1963). Handbook of Chemistry and Physics, Cleveland: Chemical Rubber

    Google Scholar 

  • Horowitz, N.H., Hobby, G.L., Hubbard, J.S. (1976). Science194, 1321–1322

    Google Scholar 

  • Horowitz, N.H., Hobby, G.L., Hubbard, J.S. (1977). J. Geophys. Res.82, 4659–4662

    Google Scholar 

  • Huguenin, R.L., Miller, K.J., Harwood, W.S. (1979). J. Mol. Evol.14, 103–132

    Google Scholar 

  • Klein, H.P., Horowitz, N.H., Levin, G.V., Oyama, V.I., Lederberg, J., Rich, A., Hubbard, J.S., Hobby, G.L., Straat, P.A., Berdahl, B.J., Carle, G.C., Brown, F.S., Johnson, R.D. (1976). Science194, 99–105

    Google Scholar 

  • Krause, A., Pawelkiewicz, J. (1954). Rocz. Chem.28, 317–327

    Google Scholar 

  • Krause, A., Binkowna, A. (1957). Rocz. Chem.31, 801–808

    Google Scholar 

  • Levin, G.V., Straat, P.A. (1976). Science194, 1322–1329

    Google Scholar 

  • Levin, G.V., Straat, P.A. (1977). J. Geophys. Res.82, 4663–4667

    Google Scholar 

  • Liu, S.C., Donahue, T.M., Cicerone, R.J., Chameides, W.L. (1976). J. Geophys. Res.81, 3111–3118

    Google Scholar 

  • Liu, S.C., Donahue, T.M. (1976). Icarus28, 231–246

    Google Scholar 

  • Liuti, G., Dondes, S., Harteck, P. (1966). J. Chem. Phys.44, 4051–4052

    Google Scholar 

  • Mel'nikov, A.K., Firsova, T.P. (1961). Zh. Neorg. Khim.6, 169–176

    Google Scholar 

  • Mills, A.A. (1977). Nature268, 614

    Google Scholar 

  • Nussinov, M.D., Chernyak, Y.B., Ettinger, J.L. (1978). Nature274, 859–861

    Google Scholar 

  • Oyama, V.I. (1972). Icarus16, 167–184

    Google Scholar 

  • Oyama, V.I., Berdahl, B.J. (1977). J. Geophys. Res.82, 4669–4676

    Google Scholar 

  • Oyama, V.I., Berdahl, B.J., Carle, G.C. (1977). Nature265, 110–114

    Google Scholar 

  • Oyama, B.I., Berdahl, B.J., Woeller, F., Lehwalt, M. (1978). Life Sci. Space Res.16, 3–8

    Google Scholar 

  • Oyama, V.I., Berdahl, B.J. (1978). in Proceedings of the Second Colloquium on Planetary Water and Polar Processes, p. 79, Hanover: U.S. Army Cold Regions Research and Engineering Laboratory

    Google Scholar 

  • Oyama, V.I., Lehwalt, M.E., Berdahl, B.J. (1979a). Life Sci. Space Res.17, 53–58

    Google Scholar 

  • Oyama, V.I., Berdahl, B.J., Woeller, F. (1979b). Life Sci. Space Res.17, 47–51

    Google Scholar 

  • Pollack, J.B., Colburn, D., Kahn, R., Hunter, J., Van Camp, W., Carlston, C.E., Wolf, M.R. (1977). J. Geophys. Res.82, 4479–4496

    Google Scholar 

  • Ponnamperuma, C., Shimoyama, A., Yamada, M., Hobo, T., Pal, R. (1977). Science197, 455–457

    Google Scholar 

  • Smith, R.N., Young, D.A., Smith, E.N., Carter, C.C. (1963). Inorg. Chem.2, 829–838

    Google Scholar 

  • Smith, R.N., Smith, R.A., Young, D.A. (1966). Inorg. Chem.5, 145–148

    Google Scholar 

  • Snow, A.W., Haubenstock, H., Yang, N.L. (1978). Macromolecules11, 77–86

    Google Scholar 

  • Sokovnin, E.I. (1963). Izv. Akad. Nauk SSSR, Otd. Khim, Nauk 181–182

  • Vol'nov, I.I., Chamova, V.N., Sergeeva, V.P., Latysheva, E.I. (1956). Zh. Neorg. Khim.1, 1937–1942

    Google Scholar 

  • Vol'nov, I.I., Shatunina, A.N. (1957). Zh. Neorg. Khim.2, 1474–1478

    Google Scholar 

  • Vol'nov, I.I., Chamova, V.N., Latysheva, E.I., Filatov, E.Y. (1967). Russ. J. Inorg. Chem.12, 1187–1188

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Oyama, V.I., Berdahl, B.J. A model of Martian surface chemistry. J Mol Evol 14, 199–210 (1979). https://doi.org/10.1007/BF01732378

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01732378

Key words

Navigation