Abstract
The hyperfine structure of the lowest1P1 state of25Mg,43Ca,87Sr,135Ba and137Ba have been measured by the level-crossing and anticrossing technique. The magnetic dipole and electric quadrupole coupling constants determined by these measurements are25Mg(3s3p1P1):A=− 7.7(5) MHz; 16 MHz>B>0 MHz,43Ca(4s4p1P1):A=− 15.3(4) MHz; ¦B¦<12 MHz,87Sr (5s5p1P1:A=− 3.4(4) MHz;B=39(4) MHz,135Ba(6s6p1P1):A=− 97.5(1.0) MHz;B=31(9)MHz,137Ba(6s6p1P1):A=−109.2(1.2) MHz;B=51(12)MHz. The results have been compared with the predictions of the Breit-Wills theory of the two-electron hyperfine structure using the experimental data on the3P states. Large discrepancies have been observed which are due to different radial wave functions of thes andp electron in the triplet and singlet system. This effect has been taken into account by fitting the data with the aid of two additional parameters. That this procedure is justified is shown by an analysis of the fine structure splitting, the life times, and the isotopic shifts in thesp configurations of group II elements.
Similar content being viewed by others
References
Reviews have been given by: Kastler, A.: J. Opt. Soc. Am.47, 460 (1957)
Series, G.W.: Rep. Progr. Phys.22, 280 (1959)
zu Putlitz, G.: Erg. d. Exakt. Natw.37, 15 (1965)
Budick, B.: Advance in Atomic and Molecular Physics, Vol. 3, ed. by R. D. Bates and I. Estermann, p. 73. New York: Academic Press 1967
zu Putlitz, G.: Atomic Physics, ed. by V.W. Hughes, B. Bederson, V. W. Cohen and F. M. J. Pichanick, p. 227. New York: Plenum Press 1969. Data are collected in Ref. 21
Breit, G., Wills, L. A.: Phys. Rev.44, 470 (1933)
Kopfermann, H.: Nuclear Moments. New York: Academic Press 1958
Lurio, A., Mandel, M., Novick, R.: Phys. Rev.126, 1758 (1962)
Mukarawa, K.: J. Phys. Soc. Japan20, 1094 (1965)
Jackson, D. A., Tuan, D. H.: Proc. Roy. Soc. A280, 323 (1964)
Lurio, A., Novick, R.: Phys. Rev.134, 608 (1964)
Blaise, J., Chantrell, H.: J. Phys. Radium18, 193 (1957)
Kluge, H.-J.: Diplomarbeit, Heidelberg (1967) (unpublished)
Kluge, H.-J., Otten, E.-W., Zimmermann, P.: Journ. de Phys.30, C1 (1969)
Breit, G.: Rev. Mod. Phys.5, 91 (1933)
Colegrove, F.D., Franken, P.A., Lewis, R.L., Sands, R.H.: Phys. Rev. Letters3, 420 (1959)
Franken, P.A.: Phys. Rev.121, 508 (1961)
Rose, M.E., Carovillano, R.L.: Phys. Rev.122, 1185 (1961)
Eck, T.G., Foldy, L.L., Wieder, H.: Phys. Rev. Letters10, 239 (1963)
Lassila, K.E.: Phys. Rev.135, 1218 (1964)
Wieder, H., Eck, T.G.: Phys. Rev.153, 103 (1967)
Budick, B., Snir, J.: Phys. Rev. Letters20, 177 (1968); Phys. Rev.178, 18 (1969)
Schüssler, H.-J.: Diplomarbeit, Heidelberg (1960) (unpublished)
Besch, H.-J., Farr, W., Otten, E.-W.: Nucl. Instr. and Meth.80, 277 (1970)
Happer, W.: Conference “The Physics of Free Atoms”. Berkeley (1966)
Lurio, A.: Phys. Rev.136, 376 (1964) (for a correction of A(1P1,137Ba), see Ref. 23)
Fuller, G.H., Cohen, V.W.: Nuclear Data Tables, A5, 433 (1968)
Olschewski, L.: Z. Physik249, 205 (1972)
Swagel, M.W., Lurio, A.: Phys. Rev.169, 114 (1968) and other references therein
Barrat, J. P.: J. Phys. Radium20, 541, 633 and 657 (1959)
Wolfe, H.C.: Phys. Rev.41, 443 (1932)
zu Putlitz, G.: Ann. Physik11, 248 (1963)
Casimir, H.B.G.: On the Interaction Between Atomic Nuclei and Electron, Teylers Tweede Genootschap, Haarlem, Holland (1936)
Schwartz, C.: Phys. Rev.97, 380 (1955)
Träger, F., Kowalski, J.: to be published in Z. Physik
Lurio, A.: Phys. Rev.126, 1768 (1962)
zu Putlitz, G.: Z. Physik175, 543 (1963)
McDermott, M.N., Lichten, W.: Phys. Rev.119, 134 (1960)
Kohler, R.: Phys. Rev.121, 1104 (1961)
Faust, W., McDermott, M.N., Lichten, W.: Phys. Rev.120, 469 (1960)
Thaddeus, P., Novick, R.: Phys. Rev.126, 1774 (1962)
Hartree, D. R., Hartree, W.: Proc. Roy. Soc. (London) A164, 167 (1938)
Klapisch, M.: La structure hyperfine magnétique des atomes et des molécules, editions du C.N.R.S. No. 164, Paris, p. 227 (1967)
King, G.W., Van Vleck, J.H.: Phys. Rev.56, 464 (1939)
Brix, P.: Z. Physik132, 579 (1952)
Araki, G.: Proc. Phys. Math. Soc. Japan19, 128 (1937);19, 592 (1937)
Vainshtein, L.A., Poluektov, I.A.: Opt. i. Spektroskopiya12, 460 (1962) [Engl. Transition Opt. Spectr. (USSR)12, 254 (1962)]
Lurio, A.: Phys. Rev.142, 46 (1966)
Condon, E.U., Shortley, G.H.: The Theory of Atomic Spectra. New York: Cambridge University Press 1935
Goldschmidt, Z. B.: Atomic Physics 3, ed. by S.J. Smith and G.K. Walters, p. 221. New York-London: Plenum Press 1973
Steudel, A., in: Krebs, K., Nelkowski, H.: Z. Physik145, 543 (1956)
Champeau, R.J., Handrich, E., Walther, H.: Z. Physik260, 361 (1973)
Bleaney, B.: Hyperfine Interactions, edited by A. J. Freeman and R. Frankel, p. 1. New York: Academic Press 1967; La structure hyperfine magnétique des atomes et des molécules, editions du C.N.R.S. No. 164, p. 13, Paris (1967)
Harvey, J.S.M.: Proc. Roy. Soc. A285, 581 (1965)
Sandars, P.G.H., Beck, J.: Proc. Roy. Soc., A289, 97 (1965)
Bordarier, Y., Judd, B.R., Klapisch, M.: Proc. Roy. Soc. A289, 81 (1965)
Sternheimer, R.M.: Phys. Rev.80, 102 (1950);84, 244 (1951);86, 316 (1953);95, 736 (1954);105, 158 (1957)
Feiertag, D., zu Putlitz, G.: Z. Physik208, 447 (1968)
Feiertag, D., Sahm, A., zu Putlitz, G.: Z. Physik255, 93 (1972)
Feiertag, D., zu Putlitz, G.: Z. Physik261, 1 (1973)
Fischer, W.: Fort. Physik18, 89 (1970)
Guthöhrlein, G.: Z. Physik214, 332 (1968)
Sandars, P.G.H., Dodsworth, B.: Hyperfine Interaction, edited by A.J. Freeman and R. Frankel, p. 120. New York: Academic Press 1967
Judd, B.R.: Proc. Phys. Soc.82, 874 (1963)
Ross, J.S., Mukarawa, K.: J. Phys. Soc. Japan19, 249 (1964)
Martin, W.C., Sugar, J., Tech, J.L.: Phys. Rev. A6, 2022 (1972)
Bauche, J., Couarraze, G., Labarthe, J.-J.: Z. Physik270, 311 (1974)
Author information
Authors and Affiliations
Additional information
This publication comprises the principal part of the dissertation of H.-J. Kluge.
The authors are indebted to Professor E.-W. Otten for many fruitfull discussions and constant encouragement and support of this work. They are also grateful to Professor W. Happer for making the levelcrossing program available to them.
Rights and permissions
About this article
Cite this article
Kluge, H.J., Sauter, H. Levelcrossing experiments in the first excited1 P 1 states of the alkaline earths. Z. Physik 270, 295–309 (1974). https://doi.org/10.1007/BF01677766
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01677766