Abstract
We derive a classical integral representation for the partition function,Z Q, of a quantum spin system. With it we can obtain upper and lower bounds to the quantum free energy (or ground state energy) in terms of two classical free energies (or ground state energies). These bounds permit us to prove that when the spin angular momentumJ → ∞ (but after the thermodynamic limit) the quantum free energy (or ground state energy) is equal to the classical value. In normal cases, our inequality isZ C(J)≦Z Q(J)≦Z C(J+1).
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On leave from the Department of Mathematics, M.I.T., Cambridge, Mass. 02139, USA. Work partially supported by National Science Foundation Grant GP-31674X and by a Guggenheim Memorial Foundation Fellowship.
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Lieb, E.H. The classical limit of quantum spin systems. Commun.Math. Phys. 31, 327–340 (1973). https://doi.org/10.1007/BF01646493
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DOI: https://doi.org/10.1007/BF01646493