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Hard body fluids again: Virial coefficients and equations of state

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Czechoslovak Journal of Physics B Aims and scope

Abstract

The table of the virial coefficientsB 2 throughB 4 of all hard body fluid models considered so far has been completed by calculating the missing coefficients. Applicability of these coefficients to predicting the thermodynamic behaviour of dense hard body fluids is assessed and certain discrepancies in the data for oblate spherocylinders are found. It is shown that by combining the Padé approximant with an appropriate analytic expression an accurate 3-parameter equation of state results.

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Authors and Affiliations

  1. Institute of Chemical Process Fundamentals, Czechosl. Acad. Sci., 105 02, Praha 6, Suchdol, Czechoslovakia

    I. Nezbeda

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  1. I. Nezbeda
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Nezbeda, I. Hard body fluids again: Virial coefficients and equations of state. Czech J Phys 35, 752–767 (1985). https://doi.org/10.1007/BF01596187

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  • DOI: https://doi.org/10.1007/BF01596187

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