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Experimental study of a biotite-bearing granitic system under water-saturated and water-undersaturated conditions

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Abstract

Phase relationships in haplogranitic melts containing ferromagnesian minerals were investigated in the temperature range 760–850°C, atP total=2 kbar,\(a_{H_2 O} \)=0.25 1.00, and at NNO buffer conditions. The compositions of coexisting biotite, orthopyroxene, magnetite and granitic melt were determined by electron microprobe. Biotite was the only Fe−Mg mineral in the starting material. It disappeared in water-undersaturated melts at temperatures above 830°C and in melts saturated with water above 810°C. Magnetite was present in all runs. Orthopyroxene became stable between 780 and 800°C. The Mg/(Mg+Fe) ratios of biotite (0,63–0,72) and orthopyroxene (0,63–0,71) are similar in water-saturated and undersaturated melts at comparable temperatures and increase slightly with increasing temperature. The solubility of Mg in haplogranitic melts is very low (0,07–0,24 wt% MgO). It increases slightly with temperature and is independent of the prevailing water activity. The solubility of Fe is low (0,91–1,37 wt% FeO); it also increases with increasing temperature, and it is higher in water-saturated than in water-undersaturated melts.

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Puziewicz, J., Johannes, W. Experimental study of a biotite-bearing granitic system under water-saturated and water-undersaturated conditions. Contr. Mineral. and Petrol. 104, 397–406 (1990). https://doi.org/10.1007/BF01575618

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