Summary
The fluidity,φ, of a molten salt is directly proportional to the relative free volume (V − V 0)/V 0. Although the parameterV 0 is closely related to the molar volume of the solid near the melting point the proportionality constant is difficult to interpret in terms of the microscopic or thermodynamic properties of the salt.
References
Hildebrand, J. H., “Viscosity and Diffusivity”, John Wiley (New York 1977).
Glasstone, S., K. J. Laidler, H. Eyring, “The Theory of Rate Processes”, McGraw-Hill (New York 1941).
Batchinski, A. J., Z. Physik. Chem.84, 643 (1913).
Sridhar, T., R. P. Chhabra, P. H. T. Uhlherr, O. E. Potter, Rheol. Acta17, 519 (1978).
Cullinan, H. T., G. Kosanovich, Amer. Inst. Chem. Engs. J.21, 195 (1975).
Kosanovich, G., H. T. Cullinan, Ind. Eng. Chem. Fund.15, 41 (1976).
Bertrand, G. L., Ind. Eng. Chem. Fund.16, 492 (1977).
Sridhar, T., O. E. Potter, J. Phys. Chem.81, 2679 (1977).
Chhabra, R. P., T. Shridhar, P. H. T. Uhlherr, O. E. Potter, Amer. Inst. Chem. Engs. J. (in press).
Hildebrand, J. H., Science174, 490 (1971).
Hildebrand, J. H., R. H. Lamoreaux, Proc. Nat. Acad. Sci. (U.S.A.)69, 3428 (1972).
Hildebrand, J. H., R. H. Lamoreaux, Proc. Nat. Acad. Sci. (U.S.A.)73, 988 (1976).
Janz G. J., “Molten Salts Handbook”, Academic Press (New York 1967).
Shimoji, M., Disc. Faraday Soc.32, 128 (1961).
Lumsden, J., “Thermodynamics of Molten Salt Mixtures”, Academic Press (New York 1966).
Copeland, James L., “Transport Properties of Ionic Liquids”, p. 47, Gordon and Breach (New York 1974).
Author information
Authors and Affiliations
Additional information
With 1 figure and 1 table
Rights and permissions
About this article
Cite this article
Chhabra, R.P., Hunter, R.J. The fluidity of molten salts. Rheol Acta 20, 203–206 (1981). https://doi.org/10.1007/BF01513063
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01513063