Summary
The theory underlying the calculation of the thermodynamic parameters controlling micellization micellar binding and solubilization has been explored. Some erroneous methods of calculation have been corrected and some problems in this field discussed.
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References
Corkill, J. M., J. F. Goodman, S. P. Harrold, andJ. R. Tate, Trans. Farad. Soc.62, 994 (1966).
Anderson, J. E. andH. Taylor, J. Pharm. Pharmac.23, 311 (1971).
Barry, B. W. andG. F. J. Russell, J. Coll. Int. Sci. (in the press).
Molyneux, P., C. T. Rhodes, andJ. Swarbrick, Trans. Farad. Soc.61, 1043 (1965).
Gurney, R. H., Ionic Processes in Solution (New York 1963).
Elworthy, P. H. andF. J. Lipscomb, J. Pharm. Pharmac.20, 790 (1968).
Tokiwa, F. andK. Ohki, Kolloid-Z. u. Z. Polymere223, 138 (1968).
Elworthy, P. H. andF. J. Lipscomb, J. Pharm. Pharmac.20, 817 (1968).
Hamori, E., Biochem. Biophys. Acta (in the press).
Bohon, R. L. andW. F. Claussen, J. Amer. Chem. Soc.73, 1571 (1951).
Shinoda, K., T. Nakagawa, B. Tamamushi, andT. Isemura, Colloidal Surfactants (New York 1963).
Patel, N. K. andH. B. Kostenbauder, J. Amer. Pharmaceut. Assoc. Sci. Ed.47, 289 (1958).
Patel, N. K. andN. E. Foss, J. Pharm. Sci.53, 94 (1964).
Donbrow, M. andC. T. Rhodes, Int. Kongr. Pharm. Wiss. Votr. Originalmit. M 1963, 397 (1964).
Donbrow, M., P. Molyneux, andC. T. Rhodes, J. Chem. Soc. A561 (1967).
Ashworth, R. W. andD. D. Heard, J. Pharm. Pharmac.18, 98S (1966).
Donbrow, M., E. Azaz, andR. Hamburger, J. Pharm. Sci.59, 1427 (1970).
Humphreys, K. J. andC. T. Rhodes, J. Pharm. Sci.57, 79 (1968).
Elworthy, P. H., A. T. Florence, and C.B. MacFarlane, Solubilization by Surface Active Agents (London 1968).
Short, M. P. andC. T. Rhodes, Nature236, 44 (1972).
Simons, K. J. andC. T. Rhodes, Die Pharmazie10, 623. (1971).
Chiou, W. L. andL. D. Smith, J. Pharm. Sci.59, 843 (1970).
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Molyneux, P., Rhodes, C.T. Calculation of the thermodynamic parameters controlling micellization, micellar binding and solubilization. Kolloid-Z.u.Z.Polymere 250, 886–890 (1972). https://doi.org/10.1007/BF01506241
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DOI: https://doi.org/10.1007/BF01506241