Skip to main content
SpringerLink
Log in

Field shifts in hafnium II

  • Published:
Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

By means of classical interference spectroscopy, using enriched isotope samples, the isotope shift between178Hf and180Hf has been measured for 33 transitions in the Hf II spectrum. For the pure Russell-Saunders terms 5d 26s 4 F and2 F the parametric analysis yields a field-shift difference of 17(2) mK produced by the second-order interaction of the electrostatic operator and the field-shift operator. Semi-empirical calculations based on the non-relativistic Hartree-Fock method reproduce this value as well as the experimental field shifts if a factor of 1.68(6) is used to scale theab initio electron densities at the nucleus. The corresponding factor for the Hf atom is much smaller. This leads to a re-evaluation of screening ratios for Hf and to a more accurate value of the nuclear parameter λ178,180 (Hf)=0.072(4) fm2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Aufmuth, P., Steudel, A., Wöbker, E.: J. Phys. B21, 2237 (1988)

    Google Scholar 

  2. Kronfeldt, H.-D., Sinn, G.: Z. Phys. D — Atoms, Molecules and Clusters14, 205 (1989)

    Google Scholar 

  3. Aufmuth, P.: J. Phys. B15, 3127 (1982)

    Google Scholar 

  4. Finckh, E., Steudel, A.: Z. Phys.141, 19 (1955)

    Google Scholar 

  5. Meggers, W.F., Corliss, C.H., Scribner, B.F.: Tables of spectral line intensities I. Washington: National Bureau of Standards 1975

    Google Scholar 

  6. Moore, C.E.: Atomic energy levels III. Washington: National Bureau of Standards 1958

    Google Scholar 

  7. Mehlhorn, R.: Ph.D. Thesis, University of California 1968

  8. Aufmuth, P., Heilig, K., Steudel, A.: At. Data Nucl. Data Tables37, 455 (1987)

    Google Scholar 

  9. Champeau, R.-J., Miladi, M.: J. Phys. (Paris)35, 105 (1974)

    Google Scholar 

  10. Bauche, J., Champeau, R.-J.: Adv. At. Mol. Phys.12, 39 (1976)

    Google Scholar 

  11. Slater, J.C.: Quantum theory of atomic structure, Vol. 2. New York: McGraw-Hill 1960

    Google Scholar 

  12. Froese Fischer, C.: Comput. Phys. Commun.14, 145 (1978)

    Google Scholar 

  13. Aufmuth, P., Kirsch, R., Steudel, A., Wöbker, E.: Z. Phys. D — Atoms, Molecules and Clusters7, 153 (1987)

    Google Scholar 

  14. Aufmuth, P., Wöbker, E.: Z. Phys. A — Atoms and Nuclei321, 65 (1985)

    Google Scholar 

  15. Aufmuth, P., Wöbker, E.: Z. Phys. D — Atoms, Molecules and Clusters2, 131 (1986)

    Google Scholar 

Download references

Author information

Author notes

  1. I. Henneberg

    Present address: Institut für Theoretische Astrophysik, Universität Tübingen, Auf der Morgenstelle 10, W-7400, Tübingen, Germany

Authors and Affiliations

  1. Institut für Atom- und Molekülphysik, Abteilung Spektroskopie, Universität Hannover, Appelstrasse 2, W-3000, Hannover 1, Germany

    P. Aufmuth, I. Henneberg, A. Siminski & A. Steudel

Authors
  1. P. Aufmuth
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Henneberg
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Siminski
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Steudel
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aufmuth, P., Henneberg, I., Siminski, A. et al. Field shifts in hafnium II. Z Phys D - Atoms, Molecules and Clusters 18, 107–112 (1991). https://doi.org/10.1007/BF01418175

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01418175

PACS

Search

Navigation