Abstract
The micellization of several monoalkylphoshpates with chain lenghts from 6 to 10 carbons have been investigated by31P and13C NMR spectroscopy with some additional electrical conductivity, density and small angle neutron scattering measurements.
The major part of this study was performed on sodium monooctylphosphate. The critical concentration of micellization is 0.14 M, the partial molar volume is 170 cm3/mole in the micellar state. Small angle neutron scattering measurements on a 0.5 molar solution lead to an aggregation number of 43. NMR studies over the whole concentration range show that the pseudophase model holds. The geometry around the polar head is found almost unchanged upon micellization. The frequency denpendence of the31P longitudinal relaxation is interpreted by an isotropic fas motion (τ R=6.5 × 10−11 for the free monomers and by a strongly anisotropic motion withD ‖/D ⊥≈10 andτ 0=(6D)−1 =1.25×10−9 s in the micellar state.
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References
Arakawa J, Pethica BA (1980) J Colloid Interface Sci 75:441
Tahara T, Satake I, Matuura R (1969) Bull Chem Soc Japan 42:1201
Nakagaki M, Handa T (1975) Bull Chem Soc Japan 48:630
Belaid S, Chachaty C (1982) J Colloid Interface Sci 86:277
Mittal KL, Lindman B (1984) Surfactants in solutions, Vol 1, p 501, Plenum Press, NY
Okabayashi H, Yoshida T, Ikeda T, Matsuura H, Kitagawa T (1982) J Am Chem Soc 104:5399
Fendler JH (1980) Acc Chem Res 13:7
Bunton CA, Diaz S, Romsted LS, Valenzuela O (1976) J Org Chem 41:3037
Cox JR jr, Ramsay OB (1964) Chem Rev 64:317
Mukerjee P, Mysels KJ (1971) Critical micelle concentrations of aqueous surfactants systems, NSRDS-NBS 36 Washington, DS, US Government printing office, see for instance page 13
Mukerjee P, Kapuan P, Meyer HG (1966) J Phys Chem 70:783
Candau S, Hirsch E, Zana R (1982) J Colloid Interface Sci 88:428
Guggenheim EA (1967) (ed) Thermodynamics, 5th, Amsterdam, North Holland publishing Co
Desnoyers JE, De Lisi R, Ostiguy C, Perron G (1979) (ed) Mittal KL, Solution chemistry of surfactants, Plenum Press, NY, Vol 1
Corkill JM, Goodman JF, Walker T (1967) Trans Faraday Soc 63:768
Bernhardt J, Pauly H (1977) J Phys Chem 81:1290
Hayter JB, Penfold J (1981) J Chem Soc Faraday Trans (1) 77:1851
Hayter JB, Penfold J (1981) Mol Phys 42:109
Hayter JB, Zemb T (1982) Chem Phys Letters 93:91
Cabane B, Duplessix R, Zemb T (1982) Proc Internat Symp Surfactants in solution, Plenum Press, NY, to be published
Cabane B (1981) J Physique 42:847
Zemb T, Chachaty C (1982) Chem Phys Letters 88:68, Erratum 91:240
Mittal KL, Lindman B (1984) Surfactants in solution, Vol 1, p 478, Plenum Press, NY
Lindeman LP, Adams JQ (1971) Anal Chem 43:1245
Drakenberg T, Lindman B (1973) J Colloid and Interface Sci 44:184
Persson BO, Drakenberg T, Londman B, (1976) J Phys Chem 80:2124
Persson BO, Drakenberg T, Londman B, (1979) J Phys Chem 83:3011
Stilbs P, Lindman B (1981) J Phys Chem 85:2587
Lindman B, Puyal MC, Kamenka N, Brun B, Gunnarsson G (1982) J Phys Chem 86:1702
Govil G, Smith ICP (1973) Biopolymers 12:2589
Tsuboi M, Kuriyagawa F, Matsuo K, Kyogoku Y (1967) Bull Chem Soc Japan 40:1813
Flory PJ (1969) Statistical mechanics of chain molecules, Willey-Interscience, NY
Chachaty C, Quaegebeur JP, Yasukawa T (1978) Chem Phys Letters 59:293
Abragam A (1961) The principles of nuclear magnetism, Clarendon press Oxford
Kohler SJ, Klein MP (1977) J Am Chem Soc 99:8290
Alexandre M, Fouchet C, Rigny P (1973) J Chim Phys 70:1073
Nery H, Marchal JP, Canet D, Cases JM (1980) J Colloid Interface Sci 77:174
Ueno M, Kishimoto H (1983) J Phys Chem 87:850
Ahlnäs T, Söderman O, Walderhaug H, Lindman B (1982) Proc Internat Symp Surfactants in solution, Plenum Press, NY, to be published
Ahlnäs T, Söderman O, Hjelm C, Lindman B, J Phys Chem, in press
Wennerström H, Lindman B, Söderman O, Drakenberg T, Rosenholm JB (1979) J Am Chem Soc 101:6860
Lindblom G, Wennerström H (1977) Biophys Chem 6:167
Nordio PL (1976) (ed) Berliner LJ, Spin Labelling, theory and applications, chap 2, Academic Press, New York
Kraut J (1961) Acta Cryst 14:1146
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Chevalier, Y., Chachaty, C. NMR investigation of the micellar properties of monoalkylphoshpates. Colloid & Polymer Sci 262, 489–496 (1984). https://doi.org/10.1007/BF01412046
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DOI: https://doi.org/10.1007/BF01412046