Abstract
With Doppler-free two-step polarization spectroscopy rovibronic levels of the 5dδ 1 Δ g state in7Li2 are excited via selected levels of the intermediateB 1 Π u state. Perturbations between the 5dδ 1 Δ g and the 4dπ 1 Π g states are observed and molecular constants of the deperturbed state are deduced.
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Mulliken, R.S.: J. Am. Chem. Soc.86, 318 (1964)
Carlson, N.W., Taylor, A.J., Jones, K.M., Schawlow, A.L.: Phys. Rev. A24, 822 (1981)
Bernheim, R.A., Gold, L.P., Tipton, T.: J. Chem. Phys.78, 3635 (1983)
Bernheim, R.A., Gold, L.P., Kelley, P.B., Tipton, T., Veirs, D.K.: J. Chem. Phys.76, 57 (1982);74, 3249 (1981);74, 2749 (1981)
Eisel, D., Demtröder, W., Müller, W., Botschwina, P.: Chem. Phys.80, 329 (1983)
Martin, S., Chevalleyre, J., Valignat, S., Perrot, J., Broyer, M., Cabaud, B., Hoareau, A.: Chem. Phys. Lett.87, 235 (1982)
Raan, A.F.J. van, Haverkort, J.E.M., Mehta, B.L., Korving, J.: J. Phys.15, L669 (1982)
Konowalow, D.K., Fish, J.L.: Chem. Phys.84, 463 (1984)
Müller, W., Flesch, J., Meyer, W.: J. Chem. Phys.80, 3297 (1984)
Herzberg, G., Jungen, Ch.: J. Mol. Spectrosc.41, 425 (1972)
Raab, M., Höning, G., Demtröder, W., Vidal, C.R.: J. Chem. Phys.76, 4370 (1982)
Teets, R.E., Kowalski, F., Hill, W.T., Carlson, N., Hänsch, T.W.: Proc. Soc. Photo Opt. Instrum. Eng. SPIE 88 (1977)
Castell, R., Demtröder, W., Fischer, A., Kullmer, R., Wickert, K.: Appl. Phys. submitted
Hessel, M.M., Vidal, C.R.: J. Chem. Phys.70, 4439 (1979)
Kusch, P., Hessel, M.M.: J. Chem. Phys.67, 586 (1977)
Engelke, F., Hage, H.: Chem. Phys. Lett.103, 98 (1983)
Rai, S.B., Hemmerling, B., Demtröder, W.: Chem. Phys. Lett. (to be published)
Herzberg, G.: Molecular spectra and molecular structure. Vol. II. New York: Van Nostrand 1950
Hougen, J.T.: The Calculation of Rotational Energy Levels. NBS Monograph 115, Washington 1970
Kovacs, I.: Rotational structure in the spectra of diatomic molecules. London: Adam Hilger LTD 1969
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Dedicated to Prof. O. Osberghaus on the occasion of his 65th birthday
Humboldt Fellow on leave from Banaras Hindu University, Varanasi, 221005, India
This work was supported by the Deutsche Forschungsgemeinschaft within the Sonderforschungsbereich 91: “Energy Transfer in Atomic and Molecular Collisions”. S.B. Rai wants to thank the Humboldt Foundation for a fellowship.
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Hemmerling, B., Rai, S.B. & Demtröder, W. Optical double resonance polarization spectroscopy of Rydberg states in7Li2 . Z Physik A 320, 135–140 (1985). https://doi.org/10.1007/BF01411933
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DOI: https://doi.org/10.1007/BF01411933