Skip to main content
SpringerLink
Log in

Infrared study of hydration and association of functional groups in a perfluorinated Nafion membrane. — Part 2

  • Polymer Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

The state of sulfonic acid groups in a thoroughly dried and slightly hydrated Nafion membrane has been analysed applying infrared spectroscopy. IR spectra in thevOH stretching vibration region were analysed in detail. A computer-curve resolution technique was used to determine band parameters of each OH band. The results of this analysis indicate a rather complex process of association of sulfonic groups in the Nafion membrane. The association of these groups in the Nafion membrane differs in several respects from that in the polystyrenesulfonic acid membrane which results from the differencies in membrane structures, both on molecular and supermolecular level.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Detoni S, Hadzi D (1957) Spectrochim Acta 11:601

    Google Scholar 

  2. Zundel G, Metzger H (1967) Spectrochim Acta, Part A 23:759

    Google Scholar 

  3. Zundel G, Metzger H, Scheuing I (1967) Z Naturforsch 22b:127

    Google Scholar 

  4. Kampschulte-Scheuing I, Zundel G (1970) J Phys Chem 74:2363

    Google Scholar 

  5. Zundel G (1969) Hydration and Intermolecular Interaction, Academic Press (New York)

    Google Scholar 

  6. Leuchs M, Zundel G (1978) J Chem Soc, Faraday Trans 2 74:2256

    Google Scholar 

  7. Thornton R, Gates BC (1973) in: Proceedings of the 5th International Congress on Catalysis, Hightower JW, Ed, pp 357–369, North Holland (Amsterdam)

    Google Scholar 

  8. Thornton R, Gates BC (1974) J Catal 34:275

    Google Scholar 

  9. Gorokhovatskaya NV, Atamanenko ID, Gerei SV, Kurilenko OD (1977) Ukr Khim Zh 43:131

    Google Scholar 

  10. Nersasian A, Johnson PR (1965) J Appl Polym Sci 9:1653

    Google Scholar 

  11. Balicheva TG, Ligus VI, Fialkov YuYa (1973) Zh Neorg Khim 18:3195

    Google Scholar 

  12. Soldatov VS, Yurevich LV (1977) J Inorg Nucl Chem 39:2069

    Google Scholar 

  13. Högfeldt E, Chiarizia R, Danesi P, Soldatov VS (1981) Chemica Scripta 18:13

    Google Scholar 

  14. Ostrowska J, Narębska A, (1983) Coll & Polym Sci 261:93

    Google Scholar 

  15. Russel DG, Senior JB (1974) Can J Chem 52:2975

    Google Scholar 

  16. Fujinaga T, Sakamoto I (1980) Pure & Appl Chem 52:1387

    Google Scholar 

  17. Nafion Perfluorosulfonic Acid Products, EI du Pont de Nemours & Co (Inc), Plastic Products & Resins Department, Wilmington, DE 19898

  18. Takamatsu T, Hashiyama M, Eisenberg A (1979) J Appl Polym Sci 24:2199

    Google Scholar 

  19. Yeo SC, Eisenberg A (1977) J Appl Polym Sci 21:875

    Google Scholar 

  20. Dębska B, Duliban J, Guzowska-Swider B (1979) Ph D Theses Technical University (Lódź)

    Google Scholar 

  21. Levy LY, Jenard A, Hurwitz HD (1980) J Chem Soc, Faraday Trans, 1 76:2558

    Google Scholar 

  22. Pauling L (1960) The Nature of the Chemical Bond, 3rd edn, Cornell Univ Press (Ithaca, New York)

    Google Scholar 

  23. Pitha J, Jones RN (1966) Can J Chem 44:3031

    Google Scholar 

  24. Pitha J, Jones RN (1967) Can J Chem 45:2347

    Google Scholar 

  25. Vandeginste BGM, De Galan L (1975) Anal Chem 47:2124

    Google Scholar 

  26. Allen GC, McMeeking RF (1978) Anal Chim Acta 103:73

    Google Scholar 

  27. Maddams WF (1980) Appl Spectrosc 34:245

    Google Scholar 

  28. Salzer R (1980) Z Chemie 20:117

    Google Scholar 

  29. Gierke TD, Munn GE, Wilson FC (1981) J Polym Sci, Polym Phys Ed 19:1687

    Google Scholar 

  30. Gierke TD, Hsu WY (1982) ACS Symp Ser 180:283 (Perfluorinated Ionomer Membr)

    Google Scholar 

  31. Mauritz KA, Hora CJ, Hopfinger AJ (1980) Adv Chem Ser 187:123 (Ions Polym)

    Google Scholar 

  32. Mauritz KA, Hopfinger AJ (1982) in: Modern Aspects of Electrochemistry, No 14, pp 425–508, Bockris JO'M, Conway BE, White RE, Eds, Plenum Publ Co (New York)

    Google Scholar 

Download references

Author information

Author notes

  1. Jadwiga Ostrowska

    Present address: Institute of Chemistry, Nicholas Copernicus University, Toruń, Poland

Authors and Affiliations

  1. Institute of Chemistry, Nicholas Copernicus University, Toruń, Poland

    Anna Narębska

Authors
  1. Jadwiga Ostrowska
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anna Narębska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ostrowska, J., Narębska, A. Infrared study of hydration and association of functional groups in a perfluorinated Nafion membrane. — Part 2. Colloid & Polymer Sci 262, 305–310 (1984). https://doi.org/10.1007/BF01410469

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01410469

Key words

Search

Navigation