Abstract
Some systems for which the binding energy increases more rapidly than linearly with the number of particles, are shown to exhibit negative specific heatc for some energies. In thermal contact with larger systems,c < 0 creates an instability, and in the canonical ensemble one sees only a phase transition. It is argued that supernovae are, in essence, a phase transition of this origin.
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On leave from the University of Vienna, Vienna, Austria.
The author would like to thank Dr. I. Wacek for her patient carrying out of the computer calculations for this work, and to Dr. A. Martin and Dr. S. Epstein for their help in studying δ2 S/δp(x) δp(x′). Furthermore, many colleagues at CERN helped with stimulating discussions.
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Thirring, W. Systems with negative specific heat. Z. Physik 235, 339–352 (1970). https://doi.org/10.1007/BF01403177
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DOI: https://doi.org/10.1007/BF01403177