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1,2,4-Triazole complexes, part X. Complexes of transition metal(II) cyanates and thiocyanates with 1-phenyl-1,2,4-triazole

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Summary

Complex formation of transition metal(II) cyanates and thiocyanates (Z) with 1-phenyl-I,2,4-triazole (1-PhTr) is described. An assignment of the i.r. spectra of free and coordinated 1-phenyl-1,2,4-triazole is given. The products are mononuclear M(1-PhTr)4Z1 and polvnuclear M(1-PhTr)2Z2 compounds. The former occur ascis andtrans isomers; the latter include bridging (thio)cvanates. A tetrahedral coordination is found for zinc complexes.

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Authors and Affiliations

  1. Dept. of Coordination Chemistry, Gorlaeus Laboratoria, Rijksuniversiteit. P.O. Box 9502, 2300, RA Leiden, The Netherlands

    Cornelis B. Donker, Jaap G. Haasnoot & Willem L. Groeneveld

Authors
  1. Cornelis B. Donker
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  2. Jaap G. Haasnoot
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  3. Willem L. Groeneveld
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Additional information

Part IX, D. W. Engelfriet, G. C. Verschoor and W. den Brinker, to be published.

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Donker, C.B., Haasnoot, J.G. & Groeneveld, W.L. 1,2,4-Triazole complexes, part X. Complexes of transition metal(II) cyanates and thiocyanates with 1-phenyl-1,2,4-triazole. Transition Met Chem 5, 368–372 (1980). https://doi.org/10.1007/BF01396963

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  • DOI: https://doi.org/10.1007/BF01396963

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